发明授权
US4777316A Manufacture of distillate hydrocarbons from light olefins in staged
reactors
失效
在分阶段反应堆中从轻质烯烃制造馏出物烃
- 专利标题: Manufacture of distillate hydrocarbons from light olefins in staged reactors
- 专利标题(中): 在分阶段反应堆中从轻质烯烃制造馏出物烃
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申请号: US118926申请日: 1987-11-10
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公开(公告)号: US4777316A公开(公告)日: 1988-10-11
- 发明人: Mohsen N. Harandi , Hartley Owen
- 申请人: Mohsen N. Harandi , Hartley Owen
- 申请人地址: NY New York
- 专利权人: Mobil Oil Corporation
- 当前专利权人: Mobil Oil Corporation
- 当前专利权人地址: NY New York
- 主分类号: C10G57/02
- IPC分类号: C10G57/02 ; B01J29/40 ; C07C2/00 ; C10G50/00 ; C07C2/02
摘要:
A semi-continuous multi-stage catalytic technique for converting lower olefinic feedstock to heavier liquid hydrocarbon product. The invention provides methods and means for: (a) contacting alkene-rich feedstock at high space velocity elevated temperature in a continuous primary stage reaction zone with shape selective medium pore zeolite oligomerization catalyst particles to convert at least a portion of the lower olefinic components to intermediate olefinic hydrocarbons, said primary stage catalyst having an average acid cracking activity of about 0.1 to 20; (b) cooling primary stage oligomerization reaction effluent from the primary stage reaction zone to condense at least a portion of the intermediate hydrocarbons, separating the cooled and partially condensed primary reactor effluent stream in a primary phase separation zone into a light gas phase stream comprising light hydrocarbons and a condensed liquid intermediate hydrocarbon stream; and (c) contacting at least an intermediate effluent portion from the primary stage with shape selective medium pore zeolite oligomerization catalyst in a high pressure fixed bed secondary stage distillate mode catalytic reactor system at elevated temperature and high pressure to provide a heavier hydrocarbon effluent stream comprising distillate hydrocarbons, said secondary stage catalyst having an acid cracking activity of at least 5. A simplified second stage reactor system permits the use of one or more fixed bed reactors to be operated intermittently.
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