发明授权
US4782181A Process for removal of high molecular weight impurities in the manufacture of purified terephthalic acid 失效
在制备纯对苯二甲酸中除去高分子量杂质的方法

  • 专利标题: Process for removal of high molecular weight impurities in the manufacture of purified terephthalic acid
  • 专利标题(中): 在制备纯对苯二甲酸中除去高分子量杂质的方法
  • 申请号: US58142
    申请日: 1987-06-04
  • 公开(公告)号: US4782181A
    公开(公告)日: 1988-11-01
  • 发明人: David E. James
  • 申请人: David E. James
  • 申请人地址: IL Chicago
  • 专利权人: Amoco Corporation
  • 当前专利权人: Amoco Corporation
  • 当前专利权人地址: IL Chicago
  • 主分类号: C07C51/487
  • IPC分类号: C07C51/487 C07C51/42
Process for removal of high molecular weight impurities in the
manufacture of purified terephthalic acid
摘要:
A process for producing fiber grade terephthalic acid is disclosed. In this process impurities having high molecular weight are eliminated by hydrogenation comprising the following steps: (a) treating an aqueous solution containing at least about 1 percent of said impure terephthalic acid with hydrogen at a temperature in the range of about 300.degree. F. to about 450.degree. F. and at a pressure sufficient to maintain the solution in the liquid phase in the presence of a supported or unsupported metallic Group VIII noble metal catalyst wherein both the metal and support components are insoluble in the solution at the temperature and at a hydrogen partial pressure of from about 30 to about 300 pounds per square inch; (b) separating the treated solution from the catalyst; (c) crystallizing terephthalic acid from the separated solution while retaining impurities and the reduced aromatic compounds dissolved in the resulting mother liquor at a temperature in the range of about 100.degree. F. to about 450.degree. F.; and (d) separating the mother liquor as a liquid phase containing dissolved impurities and reduction products from said crystals while continuing to maintain a temperature in the range of about 100.degree. F. to about 450.degree. F. whereby purified crystals of fiber grade terephthalic acid are recovered. Purified terephthalic acid is useful as a starting material in the manufacture of polyethylene terephthalate which is the principal polymer for polyester fibers, films, and resins for bottles.
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