发明授权
US4831204A Production of gasoline from light olefins with FCC gas plant improvement by olefin upgrading 失效
通过烯烃升级生产FCC轻油烯烃汽油改善汽油

Production of gasoline from light olefins with FCC gas plant improvement
by olefin upgrading
摘要:
A continuous technique for upgrading light olefinic crackate gas from hydrocarbon cracking comprising methods and means for: (a) compressing and cooling a first portion of the light crackate gas to provide a first pressurized ethene-rich vapor stream and a first condensed crackate stream rich in C.sub.3.sup.+ aliphatics; (b) contacting said first ethene-rich vapor stream under pressure with a C.sub.5 + liquid sorbent stream in a gas-liquid contact absorber column under sorption conditions to selectively absorb a major amount of C.sub.3.sup.+ components; (c) recovering a second ethene-rich vapor stream overhead from the absorber column; (d) converting said second ethene-rich vapor stream in a reaction zone in once-through contact with a fluidized bed of said medium pore zeolite catalyst solid particles under oligomerization conditions to produce an olefinic hydrocarbon effluent stream rich in C.sub.5 + hydrocarbons; (e) cooling and separating the reaction effluent stream to provide a light offgas stream and a condensed liquid hydrocarbon product stream; (f) fractionating the condensed liquid hydrocarbon product stream in the absorber column concurrently with sorption of the first ethene-rich vapor stream for recovery of liquid hydrocarbon product with an absorber bottoms liquid stream rich in C.sub.3.sup.+ components; (g) further fractionating the absorber bottoms liquid stream to provide a C.sub.3 -C.sub.4 product and a liquid hydrocarbon fraction consisting essentially of C.sub.5.sup.+ hydrocarbons; (h) recycling at least a portion of the C.sub.5.sup.+ liquid hydrocarbon fraction to the absorber column as the liquid sorbent stream; and bypassing a second portion of said light crackate gas around said absorber to the reaction zone for conversion concurrently with said second ethene-rich vapor stream.
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