发明授权
US4855330A High styrene content stable polymer polyols using epoxy resin-modified
polyols as base polyols
失效
使用环氧树脂改性多元醇作为基础多元醇的高苯乙烯含量稳定的聚合物多元醇
- 专利标题: High styrene content stable polymer polyols using epoxy resin-modified polyols as base polyols
- 专利标题(中): 使用环氧树脂改性多元醇作为基础多元醇的高苯乙烯含量稳定的聚合物多元醇
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申请号: US197868申请日: 1988-05-24
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公开(公告)号: US4855330A公开(公告)日: 1989-08-08
- 发明人: Robert G. Gastinger , John E. Hayes
- 申请人: Robert G. Gastinger , John E. Hayes
- 申请人地址: DE Wilmington
- 专利权人: Arco Chemical Technology, Inc.
- 当前专利权人: Arco Chemical Technology, Inc.
- 当前专利权人地址: DE Wilmington
- 主分类号: C08F2/44
- IPC分类号: C08F2/44 ; C08F212/10 ; C08F283/10 ; C08G18/62 ; C08G18/63
摘要:
Low viscosity polymer polyols having high styrene/acrylonitrile ratios and good stability may be achieved by the use of epoxy resin-modified polyols as the base polyols. The styrene/acrylo-nitrile ratio may be as high as 95/5 and even 100/0 in the polymer polyols. The epoxy resin-modified polyols useful as base polyols may be made by reacting a polyol initiator having an active hydrogen functionality of 3 to 8 and one or more alkylene oxides with an epoxy resin. It is preferred that only a small part of the epoxy resin-modified base polyol be initially charged to the reactor, and that the balance, a relatively larger part, be a part of the monomer feed stream to the reactor.
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