发明授权
US4918129A Process for the production of aqueous polymer dispersions, the dispersions obtainable by this process and their use for the production of coatings 失效
用于生产聚合物水分散体的方法,可通过该方法获得的分散体及其用于生产涂料的方法

Process for the production of aqueous polymer dispersions, the
dispersions obtainable by this process and their use for the production
of coatings
摘要:
Aqueous polymer dispersions useful for coating substrates are prepared by polymerization of olefinically unsaturated monomers in aqueous medium in the presence of radical formers and hydrophilically modified, urethane-group-containing emulsifiers having an average molecular weight below 30,000, wherein the urethane-group-containing emulsifiers are oligourethanes having a branched molecular structure which(i) are produced from organic polyisocyanates and organic compounds containing isocyanate-reactive groups with the reactants containing hydrophilic groups or groups convertible into hydrophilic groups and which are monofunctional or difunctional to isocyanate addition reaction, with the molar ratio of monofunctional hydrophilic components to the corresponding difunctional components being at least 2:1, and which(ii) have a content of chemically incorporated hydrophilic groups sufficient to impart the oligourethane solubility or dispersibility in water, with the proviso that, on a statistical average, at least 2.2 terminally incorporated hydrophilic groups are present per molecule.
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