公开(公告)号：US20130208724A1

公开(公告)日：2013-08-15

申请号：US13805881

申请日：2011-06-20

Applicant: Marco Colucci ,  Joachim Probst ,  Jochen Stinus

Inventor： Marco Colucci ,  Joachim Probst ,  Jochen Stinus

IPC: H04L29/06

CPC classification number: H04L69/08 ,  H04L12/40169 ,  H04L12/403 ,  H04L12/413 ,  H04L41/0816 ,  H04L2012/40228 ,  H04L2012/4026

Abstract: A method for configuring a field device that is connected to a field bus, wherein the field bus is designed for Industrial Ethernet Protocols, wherein the method comprises the following steps: analyzing a data packet transmitted on the field bus; determining an Industrial Ethernet Protocol being used in the data packet; and automatically activating a protocol stack suitable to determined Industrial Ethernet Protocol.

Abstract translation: 一种用于配置连接到现场总线的现场设备的方法，其中所述现场总线被设计用于工业以太网协议，其中所述方法包括以下步骤：分析在现场总线上发送的数据分组; 确定在数据分组中使用的工业以太网协议; 并自动激活适合于确定的工业以太网协议的协议栈。

公开(公告)号：US06962953B2

公开(公告)日：2005-11-08

申请号：US10174034

申请日：2002-06-18

Applicant: Joachim Probst ,  Martin Melchiors ,  Wieland Hovestadt ,  Michael Sonntag ,  Burkhard Köhler ,  Bernhard Jansen

Inventor： Joachim Probst ,  Martin Melchiors ,  Wieland Hovestadt ,  Michael Sonntag ,  Burkhard Köhler ,  Bernhard Jansen

IPC: C08L53/00 ,  C09D153/00 ,  C08F2/00 ,  C08L33/14 ,  C08L47/10

CPC classification number: C08L53/00 ,  C09D153/00 ,  Y10T428/31855 ,  C08L2666/04 ,  C08L2666/02

Abstract: The present invention relates to heat and storage stable vinyl polymer polyol secondary dispersions containing A) at least one vinyl polymer resin having functional groups selected from hydroxyl, carboxyl and/or sulfonic acid groups and dispersed in a water/solvent mixture in the presence of a neutralizing agent, and B) at least one amphiphilic polymer built up from a hydrophobic and a hydrophilic segment. The invention also relates to a process for the preparation of the vinyl polymer polyol secondary dispersions by preparing vinyl polymer resin A) by polymerizing a mixture of ethylenically unsaturated monomers a) in the presence of an initiator b) in a water/solvent mixture and adding at least one amphiphilic polymer B), then at least partly neutralizing and dispersing the resulting product, optionally after the addition of a further amount of water.

Abstract translation: 本发明涉及储存稳定的乙烯基聚合物多元醇二次分散体，其包含A）至少一种具有选自羟基，羧基和/或磺酸基团的官能团的乙烯基聚合物树脂，并分散在水/溶剂混合物中 中和剂，和B）由疏水和亲水链段构成的至少一种两亲性聚合物。 本发明还涉及通过制备乙烯基聚合物多元醇二次分散体来制备乙烯基聚合物多元醇二次分散体的方法，其通过在引发剂b）存在下在水/溶剂混合物中聚合烯键式不饱和单体a）的混合物并加入 至少一种两亲聚合物B），然后至少部分地中和和分散所得产物，任选地在加入另外量的水之后。

公开(公告)号：US06528573B1

公开(公告)日：2003-03-04

申请号：US09868206

申请日：2001-06-13

Applicant: Joachim Probst ,  Ulrich Biskup ,  Claus Kobusch

Inventor： Joachim Probst ,  Ulrich Biskup ,  Claus Kobusch

IPC: C08L7500

CPC classification number: C09D175/04 ,  C08F265/04 ,  C08F265/06 ,  C08G18/6254 ,  C08G18/706 ,  C09D151/003 ,  C08L2666/14 ,  C08L2666/02

Abstract: This invention relates to aqueous two-component polyurethane systems, to a process for producing them, and to their use for the production of coatings having an enhanced impact strength and good resistance to solvents.

Abstract translation: 本发明涉及水性双组分聚氨酯体系，其制备方法及其用于生产具有增强的冲击强度和良好的耐溶剂性的涂料的用途。

公开(公告)号：US5563207A

公开(公告)日：1996-10-08

申请号：US428753

申请日：1995-04-25

Applicant: Martin Brahm ,  Wolfgang Kremer ,  Lutz Schmalstieg ,  Joachim Probst ,  Werner Kubitza

Inventor： Martin Brahm ,  Wolfgang Kremer ,  Lutz Schmalstieg ,  Joachim Probst ,  Werner Kubitza

IPC: C08G18/08 ,  C08G18/00 ,  C08G18/10 ,  C08G18/28 ,  C08G18/48 ,  C08G18/70 ,  C08G18/72 ,  C08G18/80 ,  C09D5/00 ,  C09D175/00 ,  C09D175/04 ,  C08J3/00 ,  C08K3/20 ,  C08L75/00

CPC classification number: C08G18/706 ,  C08G18/283 ,  C08G18/8064

Abstract: Water-dispersible polyisocyanate compositions based on aliphatic and aromatic diisocyanates and having an NCO content, based on solids, of 6 to 21% by weight, a weight ratio of incorporated TDI units to incorporated HDI units of 6:1 to 0.1:1 and a content of ethylene oxide units, arranged within terminal polyether chains, of 5 to 40% by weight; a method for the preparation of these polyisocyanate compositions by reacting a polyisocyanate component with monovalent polyether alcohols containing ethylene oxide units at an NCO/OH equivalent ratio of 2:1 to 120:1; and aqueous coating compositions containing these polyisocyanate compositions and polyhydroxyl compounds as the binder.

Abstract translation: 基于脂肪族和芳族二异氰酸酯并且基于固体的NCO含量为6〜21重量％，结合的TDI单元与加入的HDI单元的重量比为6:1至0.1:1的水分散性多异氰酸酯组合物和 排列在末端聚醚链内的环氧乙烷单元的含量为5-40重量％; 通过使多异氰酸酯组分与NCO / OH当量比为2:1至120:1的含有环氧乙烷单元的单价聚醚醇反应来制备这些多异氰酸酯组合物的方法; 以及含有这些多异氰酸酯组合物和多羟基化合物作为粘合剂的水性涂料组合物。

公开(公告)号：US5552477A

公开(公告)日：1996-09-03

申请号：US204183

申请日：1994-03-04

Applicant: Rolf Dhein ,  Knud Reuter ,  Lothar B acker ,  Manfred Bock ,  Werner Kubitza ,  Joachim Probst

Inventor： Rolf Dhein ,  Knud Reuter ,  Lothar B acker ,  Manfred Bock ,  Werner Kubitza ,  Joachim Probst

IPC: C08G18/66 ,  C08G18/08 ,  C08G18/42 ,  C08G18/62 ,  C08G18/65 ,  C08G18/70 ,  C09D175/04 ,  C08L75/04 ,  C08L75/06

CPC classification number: C08G18/6511 ,  C08G18/0819 ,  C08G18/4288 ,  C08G18/6254 ,  C08G18/706

Abstract: An aqueous two-component coating agent whose binder consists essentially of a combination of a) a polyol component present dissolved and/or dispersed in water comprising a1) at least one water-dilutable polymerisation resin or polycondensation resin with a molecular weight Mn of over 500 possessing hydroxyl groups and a2) a reactive diluent consisting of at least one water-soluble compound with a molecular weight Mn of under 500 capable of reacting with isocyanate groups and b) a polyisocyanate component with a viscosity at 23.degree. C. of from 50 to 10 000 mPa present emulsified in the aqueous solution or dispersion, a method for producing such coating agents wherein the said polyisocyanate component is emulsified in the said aqueous solution or dispersion with the optional incorporation of auxiliary substances and additives in the system prior to adding the polyisocyanate, and the use of the coating agents for the production of air-drying and/or heat-drying coatings.

Abstract translation: PCT No.PCT / EP92 / 01983 Sec。 371日期1994年3月4日 102（e）1994年3月4日PCT PCT 1992年8月28日PCT公布。 公开号WO93 / 05087 日期1993年3月18日一种水性双组分涂布剂，其粘合剂基本上由以下组合组成：a）溶解和/或分散在水中的多元醇组分，其包含a1）至少一种水可稀释聚合树脂或缩聚树脂与分子 重量Mn超过500具有羟基，和a2）由至少一种分子量为500以下的可与异氰酸酯基反应的水溶性化合物组成的反应性稀释剂，和b）在23℃下的粘度的多异氰酸酯组分 在水溶液或分散体中乳化的50至10000立方厘米的方法，制备这种涂料的方法，其中所述多异氰酸酯组分在所述水溶液或分散体中乳化，并且可选地将辅助物质和添加剂并入系统中 在加入多异氰酸酯之前，以及使用涂布剂来生产空气干燥和/或加热干燥涂层。

公开(公告)号：US5331039A

公开(公告)日：1994-07-19

申请号：US973368

申请日：1992-11-09

Applicant: Harald Blum ,  Werner Kubitza ,  Joachim Probst ,  Michael Sonntag ,  Volker Schneider

Inventor： Harald Blum ,  Werner Kubitza ,  Joachim Probst ,  Michael Sonntag ,  Volker Schneider

IPC: C08G18/00 ,  C08G18/08 ,  C08G18/10 ,  C08G18/40 ,  C08G18/42 ,  C08G18/46 ,  C08G18/70 ,  C08L75/04 ,  C09D175/04 ,  C09D175/06 ,  C09J175/00 ,  C09J175/06 ,  H01L23/29 ,  H01L23/31 ,  C08L67/00

CPC classification number: C09D175/06 ,  C08G18/0819 ,  C08G18/10 ,  C08G18/4063 ,  C08G18/4202 ,  C08G18/706 ,  C08G2170/80

Abstract: The present invention relates to a water-based binder composition containingA) an aqueous solution or dispersion of a water-dilutable organic polyol component containing a mixture of at least 5% by weight each of at least two hydroxy-functional polymers selected fromA1) polyester resins containing hydroxyl, urethane and carboxylate groups,A2) polyester resins containing hydroxyl and carboxylate groups, but no urethane or sulfonate groups,A3) polyester resins containing hydroxyl and sulfonate groups and, optionally, carboxylate groups and/or urethane groups,A4) polyacrylate resins containing hydroxyl, carboxylate and/or sulfonate groups,A5) acrylate-grafted polyester resins containing hydroxyl, carboxylate and/or sulfonate groups, andB) a polyisocyanate component which is emulsified in the aqueous solution or dispersion A), has a viscosity at 23.degree. C. of 50 to 10,000 mPa.s and contains at least one organic polyisocyanate,wherein the NCO:OH equivalent ratio, based on the isocyanate groups of component B) and the hydroxyl groups of the polyol component present in A), is 0.2:1 to 5:1.The present invention also relates to a process for the production of a coating or sealing composition containing this aqueous binder composition.

Abstract translation: 本发明涉及水性粘合剂组合物，其包含A）水可稀释有机多元醇组分的水溶液或分散体，其含有至少5重量％的至少两种羟基官能聚合物的混合物，所述羟基官能聚合物选自A1） 含有羟基，氨基甲酸酯和羧酸酯基团的聚酯树脂，A2）含有羟基和羧酸酯基团但不含氨基甲酸酯基或磺酸酯基团的聚酯树脂，A3）含有羟基和磺酸酯基团以及任选的羧酸酯基团和/或氨基甲酸酯基团的聚酯树脂，A4） 含有羟基，羧酸酯和/或磺酸酯基的聚丙烯酸酯树脂，A5）含有羟基，羧酸酯和/或磺酸酯基团的丙烯酸酯接枝的聚酯树脂，和B）在水溶液或分散体A）中乳化的多异氰酸酯组分具有粘度 在23℃下为50至10,000mPa.s并含有至少一种有机多异氰酸酯，其中NCO:OH当量比基于异氰酸酯 组分B）的组分和A）中存在的多元醇组分的羟基为0.2:1至5:1。 本发明还涉及一种生产包含该含水粘合剂组合物的涂料或密封组合物的方法。

公开(公告)号：US5288787A

公开(公告)日：1994-02-22

申请号：US714317

申请日：1991-06-10

Applicant: Gunter Sackmann ,  Wolfgang Henning ,  Joachim Probst ,  Joachim Konig ,  Heinz Baumgen

Inventor： Gunter Sackmann ,  Wolfgang Henning ,  Joachim Probst ,  Joachim Konig ,  Heinz Baumgen

IPC: C08F2/26 ,  C08F220/12 ,  D21H17/34 ,  C08K3/20

CPC classification number: D21H17/34 ,  C08F2/26 ,  C08F220/12

Abstract: Emulsion polymers obtainable by emulsifying a mixture consisting ofA) 5 to 95 % by weight of at least one monomer from the series consisting of acrylonitrile, methacrylonitrile, optionally substituted styrene, vinyl carboxylate andB) 5 to 95 % by weight of acrylic and/or methacrylic esters,the sum of components A)+B) being 100% by weight, in the presence of an aqueous solution or dispersion of an anionically modified polyurethane, preferably containing --SO.sub.3.sup.-Me.sup.+ and/or -COO.sup.- Me.sup.+ groups (Me.sup.+ =cation, preferably H.sup.+, Na.sup.+, K.sup.+, Li.sup.+, NH.sub.4.sup.+ or a substituted ammonium ion), and subjecting the resulting emulsion to a polymerization initiated by free radicals.The emulsion polymers produced are preferably used as surface sizing agents for paper.

Abstract translation: 通过乳化由A）5-95重量％的至少一种由丙烯腈，甲基丙烯腈，任选取代的苯乙烯，乙烯基羧酸酯组成的系列中的至少一种单体的混合物得到的乳液聚合物和B）5-95重量％的丙烯酸和/ 或甲基丙烯酸酯，组分A）+ B的总和）为100重量％，在阴离子改性聚氨酯的水溶液或分散体存在下，优选含有-SO 3 Me +和/或-COO-Me +基团（Me + =阳离子，优选H +，Na +，K +，Li +，NH 4 +或取代的铵离子），并将所得乳液进行由自由基引发的聚合。 所生产的乳液聚合物优选用作纸的表面施胶剂。

公开(公告)号：US5075370A

公开(公告)日：1991-12-24

申请号：US395849

申请日：1989-08-18

Applicant: Werner Kubitza ,  Hermann Gruber ,  Joachim Probst

Inventor： Werner Kubitza ,  Hermann Gruber ,  Joachim Probst

IPC: C09D175/04 ,  C08G18/00 ,  C08G18/08 ,  C08G18/62 ,  C08G18/70 ,  C09D175/00

CPC classification number: C08G18/706 ,  C08G18/0819 ,  C08G18/6229 ,  C08G18/6254 ,  C08G18/6287

Abstract: The present invention is directed to a two-component coating composition which contains as binder componentsa) a polyol component containing at least one hydroxyl-containing polymer having chemically incorporated carboxylate and/or sulfonate groups and based on olefinically unsaturated compounds andb) a polyisocyanate component having a viscosity at 23.degree. C. of about 50 to 10,000 mPa.s and based on at least one organic polyisocyanatein quantities corresponding to an NCO/OH equivalent ratio of about 0.5:1 to 5:1, characterized in that component a) is an aqueous solution and/or dispersion of a polymer containing hydroxyl groups in which the polyisocyanate component b) is present in emulsified form.The present invention also relates to a process for the production of this coating composition which is characterized in that a polyisocyanate component having a viscosity at 23.degree. C. of about 50 to 10,000 mPa.s and based on at least one organic polyisocyanate is emulsified in an aqueous solution or dispersion of one or more polymer resins containing hydroxyl groups and chemically incorporated sulfonate and/or carboxylate groups in a quantity which makes them soluble and/or dispersible in water, the quantitative ratios between the two components corresponding to an NCO/OH equivalent ratio, based on the isocyanate groups of the polyisocyanate component and the incorporated hydroxyl groups of the polymer component, of about 0.5:1 to 5:1.

Abstract translation: 本发明涉及一种双组分涂料组合物，其包含作为粘合剂组分的a）含有至少一种具有化学结合的羧酸盐和/或磺酸盐基团并基于烯属不饱和化合物的含羟基聚合物的多元醇组分和b）多异氰酸酯 组分，其在23℃下的粘度为约50至10,000mPa.s，并且基于至少一种有机多异氰酸酯，其数量对应于约0.5:1至5:1的NCO / OH当量比，其特征在于组分a ）是含有羟基的聚合物的水溶液和/或分散体，其中多异氰酸酯组分b）以乳化形式存在。 本发明还涉及一种制备该涂料组合物的方法，其特征在于在23℃下的粘度为约50至10,000mPa.s并基于至少一种有机多异氰酸酯的多异氰酸酯组分在 含有羟基的一种或多种聚合物树脂的水溶液或分散体，并且化学掺入的磺酸盐和/或羧酸盐基团的数量使得它们可溶和/或分散在水中，两种组分之间的数量比对应于NCO / OH 基于多异氰酸酯组分的异氰酸酯基团和聚合物组分的引入羟基的当量比为约0.5:1至5:1。

公开(公告)号：US4918135A

公开(公告)日：1990-04-17

申请号：US335816

申请日：1989-04-10

Applicant: Joachim Probst ,  Walter Schafer ,  Klaus Schuster ,  Heinrich Alberts ,  Hanns P. Muller ,  Adolf Schmidt ,  Wolfhart Wieczorrek

Inventor： Joachim Probst ,  Walter Schafer ,  Klaus Schuster ,  Heinrich Alberts ,  Hanns P. Muller ,  Adolf Schmidt ,  Wolfhart Wieczorrek

IPC: B01F17/52 ,  C08F2/24 ,  C08F2/26 ,  C09D133/06

CPC classification number: C08F2/24 ,  C09D133/06

Abstract: An improved coating for heat resistant substrates is an aqueous dispersion of polymers prepared by polymerization of olefinically unsaturated monomers in an aqueous medium in the presence of radical formers and emulsifiers, wherein the emulsifiers are polyisocyanate addition products having a molecular weight below 20,000 and containing from 5 to 1000 milliequivalents of anionic structures corresponding to the following formula--NH--CO--N.sup..crclbar. --C.tbd.Nincorporated therein per 100 g of solids content.

Abstract translation: 用于耐热基材的改进的涂层是通过在自由基形成剂和乳化剂存在下在水性介质中聚合烯属不饱和单体制备的聚合物的水分散体，其中乳化剂是分子量低于20,000的多异氰酸酯加成产物，并含有5 至每1000克固体含量相应于下式-NH-CO-N（ - ） - C 3BOND N的1000毫当量阴离子结构。

公开(公告)号：US4918129A

公开(公告)日：1990-04-17

申请号：US309815

申请日：1989-02-13

Applicant: Joachim Probst ,  Josef Pedain ,  Bruno Bomer ,  Adolf Schmidt ,  Wolfhart Wieczorrek

Inventor： Joachim Probst ,  Josef Pedain ,  Bruno Bomer ,  Adolf Schmidt ,  Wolfhart Wieczorrek

IPC: C08J7/04 ,  B01F17/52 ,  C08F2/20 ,  C08F2/24 ,  C08F2/30 ,  C08F283/00

CPC classification number: C08F2/30 ,  C08F283/00

Abstract: Aqueous polymer dispersions useful for coating substrates are prepared by polymerization of olefinically unsaturated monomers in aqueous medium in the presence of radical formers and hydrophilically modified, urethane-group-containing emulsifiers having an average molecular weight below 30,000, wherein the urethane-group-containing emulsifiers are oligourethanes having a branched molecular structure which(i) are produced from organic polyisocyanates and organic compounds containing isocyanate-reactive groups with the reactants containing hydrophilic groups or groups convertible into hydrophilic groups and which are monofunctional or difunctional to isocyanate addition reaction, with the molar ratio of monofunctional hydrophilic components to the corresponding difunctional components being at least 2:1, and which(ii) have a content of chemically incorporated hydrophilic groups sufficient to impart the oligourethane solubility or dispersibility in water, with the proviso that, on a statistical average, at least 2.2 terminally incorporated hydrophilic groups are present per molecule.

Abstract translation: 可用于涂布基材的水性聚合物分散体是通过烯丙基不饱和单体在水性介质中在自由基形成剂和平均分子量低于30,000的亲水改性的含氨基甲酸酯基的乳化剂存在下聚合制备的，其中含氨基甲酸酯基的乳化剂 是具有支链分子结构的寡聚氨酯，其（i）由有机多异氰酸酯和含有异氰酸酯反应性基团的有机化合物产生，反应物含有可转化为亲水基团的亲水基团或基团，其与异氰酸酯加成反应是单官能的或双官能的， 单官能亲水性组分与相应的双官能组分的比例为至少2:1，并且（ii）具有化学引入的亲水基团的含量足以赋予低聚氨酯在水中的溶解度或分散性，条件是在sta 每个分子存在至少2.2个末端引入的亲水基团。