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US4919689A Self-reinforced silicon nitride ceramic of high fracture toughness 失效
自增强氮化硅陶瓷具有高断裂韧性

Self-reinforced silicon nitride ceramic of high fracture toughness
摘要:
A process for preparing a self-reinforced silicon nitride ceramic body of high fracture toughness comprising hot-pressing a powder mixture containing silicon nitride, magnesium oxide, yttrium oxide and calcium oxide under conditions such that densification and the in situ formation of .beta.-silicon nitride whiskers having a high aspect ratio occur. A novel silicon nitride ceramic of high fracture toughness is disclosed comprising a .beta.-silicon nitride crystalline phase wherein at least about 20 volume percent of the phase is in the form of whiskers having an average aspect ratio of at least about 2.5; a glassy second phase containing magnesium oxide, yttrium oxide, calcium oxide, and silica in a total amount not greater than about 35 weight percent; and not greater than about 10 weight percent of the total weight as other phases.
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