Invention Grant
US4921919A Method and apparatus for minimizing polymer agglomerate or lump formation in a gas-phase polypropylene polymerization reactor 失效
在气相聚丙烯聚合反应器中最小化聚合物团块或团块形成的方法和装置

Method and apparatus for minimizing polymer agglomerate or lump
formation in a gas-phase polypropylene polymerization reactor
Abstract:
The process and the system are used for carrying out the quench-cooled, vapor-phase polymerization of olefin monomer in a horizontally disposed reactor vessel which comprises contacting olefin monomer, or a mixture of olefin monomers, with a polymerization catalyst system in the presence of hydrogen in the reactor vessel to form a polymer product. The improvement comprises introducing a titanium-containing catalyst component of the catalyst system into the top side of the reactor vessel at a point adjacent to the upstream end of the reactor vessel and introducing a cocatalyst plus modifer component of the catalyst system into the top side of the reactor vessel at a distance, downstream of the point of introduction of the titanium-containing catalyst component, which is equal to 25% of the inside diameter of the reactor vessel.
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