发明授权
- 专利标题: Method for preparing fluoride glasses
- 专利标题(中): 制备氟化物玻璃的方法
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申请号: US347304申请日: 1989-05-04
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公开(公告)号: US4946490A公开(公告)日: 1990-08-07
- 发明人: Bruce T. Hall , Leonard J. Andrews , Robert C. Folweiler
- 申请人: Bruce T. Hall , Leonard J. Andrews , Robert C. Folweiler
- 申请人地址: MA Waltham
- 专利权人: GTE Laboratories Incorporated
- 当前专利权人: GTE Laboratories Incorporated
- 当前专利权人地址: MA Waltham
- 主分类号: C03C3/32
- IPC分类号: C03C3/32
摘要:
A new, simplified method of fabricating optically transparent fluoride glasses containing ZrF.sub.4 and/or HfF.sub.4 has been developed which relies on a high vacuum pretreatment for surface dehydration, melting in a rigorously inert argon atmosphere, and incorporation of a nonvolatile metallic oxidant in the melt such as InF.sub.3 or SnF.sub.4. Previous methods for making these glasses have relied on either addition of ammonium bifluoride into the batch materials, or melting in an oxidizing atmosphere (so-called reactive atmosphere processing or RAP); both of these latter techniques have significant drawbacks.
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