- 专利标题: Polymeric particles and their preparation
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申请号: US280969申请日: 1988-12-07
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公开(公告)号: US4985469A公开(公告)日: 1991-01-15
- 发明人: Gerald K. Chip , Alfred Rudin
- 申请人: Gerald K. Chip , Alfred Rudin
- 申请人地址: GB2 London
- 专利权人: Tioxide Group
- 当前专利权人: Tioxide Group
- 当前专利权人地址: GB2 London
- 优先权: GBX8729399 19871217
- 主分类号: C08F265/06
- IPC分类号: C08F265/06 ; C08F265/00 ; C08F265/02 ; C08F265/04 ; C08F267/02 ; C08F285/00
摘要:
Polymer particles or beads for use as opacifiers in paints are described in which a core is provided with a hard sheath and the particle has one or more voids produced by reaction with a nonvolatile permanent or fixed base. The sheath is a copolymer of an ethylenically unsaturated aliphatic monomer free of acid groups and at least 2 percent by weight of a soft ester-containing monomer and optionally styrene in an amount of up to 25 mole percent. The core is formed from an ethylenically unsaturated monomer with acid functionality.The sheath polymer has a glass transition temperature of at least 40.degree. C. The particles have a size of up to 40000 nanometers before swelling the core by some 150 to 2000 percent.
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