- 专利标题: Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers
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申请号: US359131申请日: 1989-05-31
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公开(公告)号: US5008356A公开(公告)日: 1991-04-16
- 发明人: Naoshi Ishimaru , Toshiyuki Tsutsui , Akinori Toyota , Norio Kashiwa
- 申请人: Naoshi Ishimaru , Toshiyuki Tsutsui , Akinori Toyota , Norio Kashiwa
- 申请人地址: JPX Tokyo
- 专利权人: Mitsui Petrochemical Industries, Ltd.
- 当前专利权人: Mitsui Petrochemical Industries, Ltd.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX62-45152 19870302; JPX62-312112 19871211; JPX62-315206 19871215; JPX63-19622 19880201
- 主分类号: C08F4/659
- IPC分类号: C08F4/659 ; C08F4/6592 ; C08F210/00 ; C08F210/06 ; C08F210/14 ; C08F232/00
摘要:
A cyclo-olefinic random copolymer composed of an alpha-olefin component having 3 to 20 carbon atoms and a cyclo-olefin component,(i) said copolymer containing 5 to 99 mole % of recurring units derived from said alpha-olefin component having 3 to 20 carbon atoms and 1 to 95 mole % of recurring units derived from said cyclo-olefin component, and(ii) said copolymer having an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of from 0.01 to 10 dl/g; and an olefinic random copolymer composed of (A) an olefin component having 3 to 20 carbon atoms and (B) a cyclic polyene component and as required, (C) a cyclo-olefin component,(i) said copolymer containing 5 to 99 mole % of recurring units derived from said alpha-olefin component (A) having 3 to 20 carbon atoms and 1 to 95 mole % of recurring units derived from said cyclic polyene component (B) and 0 to 90 mole % of recurring units derived from said cyclo-olefin component (C), and(ii) said copolymer having an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of from 0.01 to 10 dl/g; and a process for production thereof. Also provided is a process for producing a cyclo-olefinic random copolymer, which comprises copolymerizing an alpha-olefin and a cyclo-olefin in the presence of a catalyst formed from(A) a compound of a transition metal of Group IVB of the periodic table having as a ligand a multidentate coordination compound in which at least two conjugated cycloalkadienyl groups or substituted products thereof are bonded via a lower alkylene group, and(B) an aluminoxane.