发明授权
US5026862A Process for the preparation of 1.R, cis cyclopropane di-carboxylic acid
derivatives
失效
制备1.R,顺式环丙烷二羧酸衍生物的方法
- 专利标题: Process for the preparation of 1.R, cis cyclopropane di-carboxylic acid derivatives
- 专利标题(中): 制备1.R,顺式环丙烷二羧酸衍生物的方法
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申请号: US416718申请日: 1989-10-03
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公开(公告)号: US5026862A公开(公告)日: 1991-06-25
- 发明人: Jean Tessier , Jean-Pierre Demoute
- 申请人: Jean Tessier , Jean-Pierre Demoute
- 申请人地址: FRX Paris
- 专利权人: Roussel Uclaf
- 当前专利权人: Roussel Uclaf
- 当前专利权人地址: FRX Paris
- 优先权: FRX8207870 19820506
- 主分类号: C07C69/743
- IPC分类号: C07C69/743 ; A01N53/10 ; C07C67/00 ; C07C67/343 ; C07C67/44 ; C07C69/608 ; C07C69/747 ; C07C253/30 ; C07C255/39 ; C07C325/00 ; C07C327/12 ; C07C327/22 ; C07F9/6571
摘要:
A novel process for the preparation of compounds in all their possible isomeric forms of the formula ##STR1## wherein R is selected from the group consisting of hydrogen, alkyl of 1 to 18 carbon atoms, an easily cleavable derivative of the alcohol R-OH and a residue of an alcohol used in the pyrethrinoid series and when Y is --COOR' or --COSR', W is hydrogen and W is halogen when Y is --COOR' and R' is selected from the group consisting of hydrogen, optionally unsaturated alkyl of 1 to 18 carbon atoms and optionally substituted with at least one functional group, aryl optionally substituted with at least one functional group and heterocycle optionally substituted with at least one functional group and when W is hydrogen, the double bond has Z configuration and when W is halogen, the double bond has the E configuration comprising reacting a compound of the formula ##STR2## wherein R has the above definition with a compound of the formula ##STR3## wherein W and Y have the above definitions and A is alkylene of 1 to 18 carbon atoms attached to the two oxygen atoms fixed on the phosphorus atom to obtain a compound of formula I with the double bond having the Z configuration when W is hydrogen and having the E configuration when W is halogen, the cyclopropane and the carboxyl of Y being in both cases in the cis position with respect to the double bond and novel intermediates.
公开/授权文献
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