发明授权
US5053573A Reduction of benzene content of reformate by reaction with cycle oils
失效
通过与循环油反应来还原重整产物的苯含量
- 专利标题: Reduction of benzene content of reformate by reaction with cycle oils
- 专利标题(中): 通过与循环油反应来还原重整产物的苯含量
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申请号: US583273申请日: 1990-09-14
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公开(公告)号: US5053573A公开(公告)日: 1991-10-01
- 发明人: Diane V. Jorgensen , Ajit V. Sapre
- 申请人: Diane V. Jorgensen , Ajit V. Sapre
- 申请人地址: VA Fairfax
- 专利权人: Mobil Oil Corporation
- 当前专利权人: Mobil Oil Corporation
- 当前专利权人地址: VA Fairfax
- 主分类号: C10G29/20
- IPC分类号: C10G29/20 ; C10G59/02 ; C10G63/00
摘要:
Conversion of benzene to heavier aromatics by contact with alkyl polynucleararomatics, preferably FCC heavy cycle oil, in the presence of an alkylation/transalkylation catalyst is disclosed. Efficient conversion of relatively dilute benzene in reformate is possible. Use of alkyl polynucleararomatics as a source of alkyl groups, with reduced use of monocyclic alkyl aromatics, permits robust reaction conditions to be used without a net formation of benzene by dealkylation. The process preferably uses a solid zeolite based acidic catalyst disposed in a fixed, moving or fluid bed reactor. Preferred catalysts comprise MCM-22 or ZSM-5.