发明授权
- 专利标题: Continuous preparation of aromatic polycondensates
- 专利标题(中): 连续制备芳香族聚氧乙烯
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申请号: US365130申请日: 1989-06-12
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公开(公告)号: US5068308A公开(公告)日: 1991-11-26
- 发明人: Gunter Pipper , Gerhard Heinz , Bernd Hisgen
- 申请人: Gunter Pipper , Gerhard Heinz , Bernd Hisgen
- 申请人地址: DEX Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DEX Ludwigshafen
- 优先权: DEX3820361 19880615
- 主分类号: C08G63/19
- IPC分类号: C08G63/19 ; C08G63/60 ; C08G63/688 ; C08G63/78 ; C08G69/32 ; C08G69/44 ; C08G73/16 ; C08G75/26
摘要:
Aromatic polycondensates are prepared in a continuous process froma) aromatic hydroxy-, thio- and/or amino-carboxylic acids,b) aromatic dihydroxy-, dithio-, diamino- and/or hydroxy-amino compounds,c) urea as an optional component andd) a molar amount equivalent to the sum of components b) and c) of aromatic dicarboxylic acids,by1. reacting components a), b), d) and optionally c) with lower fatty acid anhydrides in excess at from 140.degree. to 280.degree. C. with distillative removal of fatty acids and fatty acid anhydrides,2. passing the oligomer mixture downward through a perpendicular precondensation zone to form a two-phase mixture of prepolymers and vaporous fatty acids,3. separating the prepolymers from the vaporous fatty acids and4. condensing the prepolymer in a condensation zone to give a granulable polycondensate.
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