发明授权
- 专利标题: Preparation of branched polycarbonate from oligomeric cyclic polycarbonate and polyhydric phenol
- 专利标题(中): 从低聚环状聚碳酸酯和多元酚制备支化聚碳酸酯
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申请号: US521495申请日: 1990-05-10
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公开(公告)号: US5097008A公开(公告)日: 1992-03-17
- 发明人: Herman O. Krabbenhoft , Eugene P. Boden
- 申请人: Herman O. Krabbenhoft , Eugene P. Boden
- 申请人地址: NY Schenectady
- 专利权人: General Electric Company
- 当前专利权人: General Electric Company
- 当前专利权人地址: NY Schenectady
- 主分类号: C08G64/14
- IPC分类号: C08G64/14 ; C08G64/30 ; C08G75/28
摘要:
Branched polycarbonates are prepared by melt equilibration of aromatic cyclic polycarbonate oligomers with a polyhydric phenol having more than two hydroxy groups per molecule, preferably 1,1,1-tris-(4-hydroxyphenyl)ethane, in the presence of a carbonate equilibration catalyst, preferably tetrabutylammonium tetraphenylborate. In an additional embodimetn of the invention, a linear aromatic polycarbonate is added to the reaction mixture. Branched polycarbonates prepared according to this inventin have high melt strength and high shear sensitivity characteristics and are useful in extrusion and injection molding processing applications and particularly useful in blow molding applications for preparing relatively large articles and panels.
公开/授权文献
- US5651834A Method and apparatus for CO.sub.2 cleaning with mitigated ESD 公开/授权日:1997-07-29
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