发明授权
- 专利标题: Process for the production of olefins by combined methane oxidative coupling/hydrocarbon pyrolysis
- 专利标题(中): 通过组合甲烷氧化偶合/烃热解生产烯烃的方法
-
申请号: US493729申请日: 1990-03-14
-
公开(公告)号: US5118898A公开(公告)日: 1992-06-02
- 发明人: Ralph J. Tyler , James H. Edwards , Peter J. Jackson
- 申请人: Ralph J. Tyler , James H. Edwards , Peter J. Jackson
- 申请人地址: AUX Melbourne AUX Campbell ACT
- 专利权人: The Broken Hill Proprietary Company Limited,Commonwealth Scientific & Industrial Research Organization
- 当前专利权人: The Broken Hill Proprietary Company Limited,Commonwealth Scientific & Industrial Research Organization
- 当前专利权人地址: AUX Melbourne AUX Campbell ACT
- 优先权: AUXPJ5021 19890630
- 主分类号: B01J21/16
- IPC分类号: B01J21/16 ; B01J23/02 ; B01J27/232 ; B01J37/08 ; C07C2/84
摘要:
A process for the production of ethylene from a methane rich gas stream and an ethane rich gas stream. The process comprises the steps of:(a) introducing the methane rich gas stream together with molecular oxygen into a lower zone of a fluidized-bed of particles which are catalytically active in promoting an exothermic oxidative coupling reaction to produce ethylene and other hydrocarbons,(b) mixing the ethane rich gas stream into the fluidized-bed above the level at which substantially all of the molecular oxygen has been consumed, and(c) subjecting the mixture resulting from step (b) to an endothermic pyrolysis reaction in an upper zone of the fluidized-bed to produce further ethylene and other olefinically unsaturated hydrocarbons.The process is characterized in that the pyrolysis step (c) is carried out substantially without the addition of heat to the reactor, other than the heat content of the methane rich and ethane rich gas streams and the heat generated by the exothermic oxidative coupling reaction. The fluidized bed particles are desirably caused to circulate within the reactor in such a manner that there is an efficient transfer of exothermic heat from the oxidative coupling zone to the pyrolysis zone so that the reactions of steps (a) and (c) occur at substantially the same temperature.
公开/授权文献
信息查询