发明授权
US5155138A Expandable thermoplastic microspheres and process for the production and
use thereof
失效
可膨胀的热塑性微生物及其生产和使用的方法
- 专利标题: Expandable thermoplastic microspheres and process for the production and use thereof
- 专利标题(中): 可膨胀的热塑性微生物及其生产和使用的方法
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申请号: US789323申请日: 1991-11-08
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公开(公告)号: US5155138A公开(公告)日: 1992-10-13
- 发明人: Jorgen Lundqvist
- 申请人: Jorgen Lundqvist
- 申请人地址: SEX Stockholm
- 专利权人: Casco Nobel AB
- 当前专利权人: Casco Nobel AB
- 当前专利权人地址: SEX Stockholm
- 优先权: SEX9003600 19901112
- 主分类号: B01J13/14
- IPC分类号: B01J13/14 ; C06B23/00 ; C08F2/18 ; C08F2/44 ; C08J9/20 ; C08J9/26 ; C08K3/10 ; C09D7/12 ; C09D11/02 ; D21H21/54
摘要:
A method for producing expandable thermoplastic microspheres by polymerisation in a reaction vessel of an ethylenically unsaturated monomer or a mixture of monomers in an aqueous suspension in the presence of a condensed propellant. In the method, the monomer or monomer mixture is suspended in the aqueous medium in the presence of a powder stabilizer which consists of a salt or hydroxide of any of the metals Ca, Mg, Ba, Fe, Zn, Ni or Mn. The powder stabilizer is insoluble in the aqueous medium at the pH the aqueous medium has at the polymerisation. The aqueous medium has at the polymerization. The aqueous medium may also contain a co-stabilizer. The method further comprises the step of washing off the powder stabilizer from the microspheres after the polymerization by lowering the pH of the aqueous medium by the addition of acid. Alternatively, amphoteric hydroxides can also be dissolved by a pH increase. The invention also relates to microspheres produced according to the method of the invention, and to the use thereof.
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