发明授权
- 专利标题: Self-reinforced silicon nitride ceramic of high fracture toughness
- 专利标题(中): 自增强氮化硅陶瓷具有高断裂韧性
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申请号: US826315申请日: 1992-01-24
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公开(公告)号: US5160508A公开(公告)日: 1992-11-03
- 发明人: Aleksander J. Pyzik , Harold E. Rossow , Douglas B. Schwarz , Donald R. Beaman , Barbara M. Pyzik , William J. Dubensky
- 申请人: Aleksander J. Pyzik , Harold E. Rossow , Douglas B. Schwarz , Donald R. Beaman , Barbara M. Pyzik , William J. Dubensky
- 申请人地址: MI Midland
- 专利权人: The Dow Chemical Company
- 当前专利权人: The Dow Chemical Company
- 当前专利权人地址: MI Midland
- 主分类号: C04B35/593
- IPC分类号: C04B35/593 ; C04B35/645 ; C04B35/80
摘要:
A process for preparing a self-reinforced silicon nitride ceramic body of high fracture toughness comprising hot-pressing a powder mixture containing silicon nitride, a densification aid such as sodium oxide, a conversion aid such as lanthanum oxide and a compound, such as gallium oxide, which enhances growth of .beta.-silicon nitride whiskers-under conditions such that densification and the in situ formation of .beta.-silicon nitride whiskers having a high aspect ratio occur. A novel silicon nitride ceramic of high fracture toughness and high fracture strength is disclosed comprising a .beta.-silicon nitride crystalline phase wherein at least about 20 volume percent of the phase is in the form of whiskers having an average aspect ratio of at least about 2.5; a glassy second phase containing the densificaton aid, the conversion aid, the compound which enhances growth of .beta.-silicon nitride whiskers, and an amount of silica; and not greater than about 10 weight percent of the total weight as other phases. The glassy phase may also include a minor amount, e.g., up to 5.0 weight percent, based upon total weight of the ceramic, of aluminum nitride or boron nitride. The glassy phase optionally includes an amount of a secondary reinforcing material such as silicon carbide whiskers.