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US5252755A Preparation of 4-hydroxymethyltetrahydropyrans 失效
4-羟甲基四氢吡喃的制备

Preparation of 4-hydroxymethyltetrahydropyrans
摘要:
A process for the preparation of 4-hydroxymethyltetrahydropyrans of the formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are hydrogen, C.sub.1 - to C.sub.12 -alkyl, C.sub.3 - to C.sub.8 -cycloalkyl, aryl or C.sub.7 - to C.sub.20 -aralkyl, comprises reacting a tetrahydropyrancarboxylic ester of the formula II ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are as defined above, and R.sup.5 is hydrogen or C.sub.1 - to C.sub.12 -alkyl, at from 50.degree. to 400.degree. C. and at from 1 to 400 bar in the presence of hydrogen and a hydrogenation catalyst.
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