发明授权
- 专利标题: Method of producing liquid hydrocarbons from natural gas, in the presence of a catalyst based on zeolite and gallium
- 专利标题(中): 在基于沸石和镓的催化剂存在下,从天然气生产液态烃的方法
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申请号: US886226申请日: 1992-05-21
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公开(公告)号: US5288935A公开(公告)日: 1994-02-22
- 发明人: Fabio Alario , Charles Cameron , Jean-Francois Joly
- 申请人: Fabio Alario , Charles Cameron , Jean-Francois Joly
- 申请人地址: FRX Rueil Malmaison
- 专利权人: Institut Francais du Petrole
- 当前专利权人: Institut Francais du Petrole
- 当前专利权人地址: FRX Rueil Malmaison
- 优先权: FRX9106195 19910521
- 主分类号: B01J29/70
- IPC分类号: B01J29/70 ; C07B61/00 ; C07C2/00 ; C07C2/84 ; C07C15/00 ; C07C15/02 ; C10G2/00 ; C10G57/02 ; C07C2/78
摘要:
The invention concerns a method of producing liquid hydrocarbons from natural gas, characterized in that:a) the natural gas is separated in (2) into at least two fractions, a first fraction of gas enriched with methane and a second fraction enriched with C2+ alkanesb) the methane is selectively oxidised in (7a) by molecular oxygen in the presence of a catalyst for oxidizing linkage of methanec) the fraction enriched with C2+ alkanes is at least partly mixed with the effluent from selective oxidation, when at least 80% of the molecular oxygen introduced at stage (b) has already been consumed at stage (b)d) the mixture resulting from stage (c) is pyrolysed in (7b)e) when the temperature of the mixture from stage (d) has been brought to a temperature from 300.degree. to 750.degree. C. and more particularly from 420.degree. to 550.degree. C., at least part of the olefins is converted to aromatics in (11c), in the presence of a special catalyst containing a zeolite, gallium, one or more Group VIII metals and/or rhenium, one or more additional metals selected from tin, lead, indium, germanium and thallium, possibly an alkali metal or alkaline earth metal and possibly a matrix.
公开/授权文献
- US4759329A Throttle valve control apparatus for an engine 公开/授权日:1988-07-26
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