The present invention provides a multilayer composite sliding material with excellent seizure resistance property having a steel plate or a steel plate having surfaces plated with copper or the like; a bond layer having a thickness of 0.05 to 0.5 mm, formed on the steel plate, and made of a sintered powder material consisting of 5 to 16% Sn, 0 to 15% Pb, 0 to 0.5% P and balance essentially Cu; and an alloy layer having a thickness of 0.1 to 1.0 mm, formed on the bond layer, and made of a sintered powder material consisting of 5 to 16% Sn, 1 to 12% MoS.sub.2 and balance essentially Cu. In a modified form of the alloy layer, not more than 20% Pb, not more than 1% P or not more than 12% Ni may be added. MoS.sub.2 powder may be coated with Cu or Ni.