发明授权
- 专利标题: Ethylene/propylene copolymer rubbers
- 专利标题(中): 乙烯/丙烯共聚物橡胶
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申请号: US84287申请日: 1993-06-28
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公开(公告)号: US5332793A公开(公告)日: 1994-07-26
- 发明人: Kevin J. Cann
- 申请人: Kevin J. Cann
- 申请人地址: CT Danbury
- 专利权人: Union Carbide Chemicals & Plastics Technology Corporation
- 当前专利权人: Union Carbide Chemicals & Plastics Technology Corporation
- 当前专利权人地址: CT Danbury
- 主分类号: C08F2/34
- IPC分类号: C08F2/34 ; C08F4/60 ; C08F4/68 ; C08F10/00 ; C08F10/02 ; C08F210/00 ; C08F210/02 ; C08F210/16
摘要:
A process for the production of EPRs comprising contacting ethylene, propylene, and optionally, a diene, under polymerization conditions, with a catalyst system comprising:(A) a catalyst precursor comprising:(i) a vanadium compound, which is the reaction product of(a) VX.sub.3 wherein each X is independently chlorine, bromine, or iodine; and(b) an electron donor, which is a liquid, organic Lewis base in which VX.sub.3 is soluble;(ii) a modifier having the formula BX.sub.3 or AlR.sub.(3-a) X.sub.a wherein each R is independently alkyl having 1 to 14 carbon atoms; each X is as defined above; and a is 1 or 2; and(iii) a support for said vanadium compound and modifier,said catalyst precursor being in an independent or prepolymerized state,wherein said independent catalyst precursor or said prepolymerized catalyst precursor have been pre-oxidized with an oxidant in an amount sufficient to increase the oxidation state of the vanadium by at least one;(B) a cocatalyst consisting essentially of a compound having the formula AlR.sub.(3-a) X.sub.a and, optionally, a compound having the formula AlR.sub.3 wherein R, X, and a are as defined above; and,(C) optionally, a promoter, which is a chlorinated ester having at least 2 chlorine atoms; a saturated or unsaturated aliphatic halocarbon having at least 3 carbon atoms and at least 6 halogen atoms; or a haloalkyl substituted aromatic hydrocarbon wherein the haloalkyl substituent has at least 3 halogen atoms.
公开/授权文献
- USD421471S Free standing golf putter head 公开/授权日:2000-03-07
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