发明授权
US5347045A Sulfonated 2,2'-bis (diphenylphosphinomethyl)-1,1'-binaphthalenes, process for their preparation and their use in a process for the hydroformylation of olefinically unsaturated compounds 失效
磺化的2,2'-双(二苯基膦基甲基)-1,1'-联萘,其制备方法及其在烯属不饱和化合物的加氢甲酰化方法中的应用

Sulfonated 2,2'-bis (diphenylphosphinomethyl)-1,1'-binaphthalenes,
process for their preparation and their use in a process for the
hydroformylation of olefinically unsaturated compounds
摘要:
Sulfonated diphosphines of the formula ##STR1## in which Ar is m-C.sub.6 H.sub.4 --SO.sub.3 M, M is hydrogen, ammonium, a monovalent metal, or the chemical equivalent of a polyvalent metal; Ph is phenyl; the m's are individually 1 or 2, and the n's are individually 0, 1, or 2. A method of their preparation and the hydroformylation of olefins and olefinically unsaturated compounds using these compounds as a constituent of water-soluble catalyst systems are also disclosed.
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