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1.发明授权Sulfonated 2,2'-bis (diphenylphosphinomethyl)-1,1'-binaphthalenes, process for their preparation and their use in a process for the hydroformylation of olefinically unsaturated compounds 失效磺化的2,2'-双（二苯基膦基甲基）-1,1'-联萘，其制备方法及其在烯属不饱和化合物的加氢甲酰化方法中的应用
公开(公告)号：US5347045A
公开(公告)日：1994-09-13
申请号：US66553
申请日：1993-05-25
申请人： Wolfgang A. Herrmann , Rainer Manetsberger , Helmut Bahrmann , Christian Kohlpaintner , Peter Lappe
发明人： Wolfgang A. Herrmann , Rainer Manetsberger , Helmut Bahrmann , Christian Kohlpaintner , Peter Lappe
CPC分类号： C07F9/5027 , B01J31/2452 , C07C45/50 , B01J2231/321 , B01J2531/0266 , B01J2531/822 , B01J2531/96
摘要： Sulfonated diphosphines of the formula ##STR1## in which Ar is m-C.sub.6 H.sub.4 --SO.sub.3 M, M is hydrogen, ammonium, a monovalent metal, or the chemical equivalent of a polyvalent metal; Ph is phenyl; the m's are individually 1 or 2, and the n's are individually 0, 1, or 2. A method of their preparation and the hydroformylation of olefins and olefinically unsaturated compounds using these compounds as a constituent of water-soluble catalyst systems are also disclosed.
摘要翻译： 其中Ar是m-C6H4-SO3M的式“IMAGE”的磺化二膦，M是氢，铵，一价金属或多价金属的化学当量; Ph为苯基; m是单独的1或2，n分别为0,1或2.它们的制备方法和使用这些化合物作为水溶性催化剂体系的组分的烯烃和烯属不饱和化合物的加氢甲酰化也被公开。
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2.发明授权Sulfonated 2,2'-bis (diphenylphosphinomethyl)-1,1'-binaphthalenes, process for their preparation and their use in a process for the hydroformylation of olefinically unsaturated compounds 失效磺化的2,2'-双（二苯基膦基甲基）-1,1'-联萘，其制备方法及其在烯属不饱和化合物的加氢甲酰化方法中的应用
公开(公告)号：US5481045A
公开(公告)日：1996-01-02
申请号：US240902
申请日：1994-05-11
申请人： Wolfgang A. Herrmann , Rainer Manetsberger , Helmut Bahrmann , Christian Kohlpaintner , Peter Lappe
发明人： Wolfgang A. Herrmann , Rainer Manetsberger , Helmut Bahrmann , Christian Kohlpaintner , Peter Lappe
CPC分类号： C07F9/5027 , B01J31/2452 , C07C45/50 , B01J2231/321 , B01J2531/0266 , B01J2531/822 , B01J2531/96
摘要： Sulfonated diphosphines of the formula ##STR1## in which Ar is m-C.sub.6 H.sub.4 -SO.sub.3 M, M is hydrogen, ammonium, a monovalent metal, or the chemical equivalent of a polyvalent metal; Ph is phenyl; the m's are individually 1 or 2, and the n's are individually 0, 1, or 2. A method of their preparation and the hydroformylation of olefins and olefinically unsaturated compounds using these compounds as a constituent of water-soluble catalyst systems are also disclosed.
摘要翻译： 其中Ar是m-C6H4-SO3M的式“IMAGE”的磺化二膦，M是氢，铵，一价金属或多价金属的化学当量; Ph为苯基; m是单独的1或2，n分别为0,1或2.它们的制备方法和使用这些化合物作为水溶性催化剂体系的组分的烯烃和烯属不饱和化合物的加氢甲酰化也被公开。
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3.发明授权3,4-dimethyl-2,5,6-tris(p-sulfonatophenyl)-1-phosphanorbornadiene, process for the preparation thereof and process for the hydroformylation of olefinnically unsaturated compounds 失效3,4-二甲基-2,5,6-三（对磺酸苯基）-1-膦酰基降冰片二烯，其制备方法和烯烃不饱和化合物的加氢甲酰化方法
公开(公告)号：US5312951A
公开(公告)日：1994-05-17
申请号：US78975
申请日：1993-06-17
CPC分类号： B01J31/248 , C07C45/50 , C07F15/008 , C07F9/65683 , B01J2231/321 , B01J2531/822
摘要： The chemical compound 3,4-dimethyl-2,5,6-tris(p-sulfonatophenyl)-1-phosphanorbernadiene, a process for the preparation thereof and a process for the hydroformylation of olefinically unsaturated compounds with the use of catalysts which contain the aforementioned chemical compound.
摘要翻译： 化合物3,4-二甲基-2,5,6-三（对磺酸苯基）-1-膦酰苯二烯，其制备方法以及烯属不饱和化合物的加氢甲酰化方法，其中使用含有 上述化合物。
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4.发明授权Sulfonated 2,2'-bis (Diphenylphosphinomethyl)-1,1'-binaphthalenes, process for their preparation and their use in a process for the hydroformylation of olefinically unsaturated compounds 失效磺化的2,2'-双（二苯基膦基甲基）-1,1'-联萘，其制备方法及其在烯属不饱和化合物的加氢甲酰化方法中的应用
公开(公告)号：US5565398A
公开(公告)日：1996-10-15
申请号：US552289
申请日：1995-11-02
CPC分类号： C07F9/5027 , B01J31/2452 , C07C45/50 , B01J2231/321 , B01J2531/0266 , B01J2531/822 , B01J2531/96
摘要： Sulfonated diphosphines of the formula ##STR1## in which Ar is m--C.sub.6 H.sub.4 --SO.sub.3 M, M is hydrogen, ammonium, a monovalent metal, or the chemical equivalent of a polyvalent metal; Ph is phenyl; the m's are individually 1 or 2, and the n's are individually 0, 1, or 2. A method of their preparation and the hydroformylation of olefins and olefinically unsaturated compounds using these compounds as a constituent of water-soluble catalyst systems are also disclosed.
摘要翻译： 其中Ar是m-C6H4-SO3M的式“IMAGE”的磺化二膦，M是氢，铵，一价金属或多价金属的化学当量; Ph为苯基; m是单独的1或2，n分别为0,1或2.它们的制备方法和使用这些化合物作为水溶性催化剂体系的组分的烯烃和烯属不饱和化合物的加氢甲酰化也被公开。
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公开(公告)号：US5451698A
公开(公告)日：1995-09-19
申请号：US264720
申请日：1994-06-23
申请人： Helmut Bahrmann , Peter Lappe , Wolfgang A. Herrmann , Rainer Manetsberger , Guido Albanese , Klaus Bergrath
发明人： Helmut Bahrmann , Peter Lappe , Wolfgang A. Herrmann , Rainer Manetsberger , Guido Albanese , Klaus Bergrath
IPC分类号： B01J21/02 , C07B61/00 , C07F9/50 , C07C309/32
CPC分类号： C07F9/5054
摘要： The sulfonation of arylphosphines, i.e. mono-, di-, oligo- and polyphosphines, which contain at least one aromatic radical capable of being sulfonated, is carried out in the presence of a Lewis acid at 0.degree. to 80.degree. C. The process avoids side-reactions, in particular the formation of phosphine oxides. In treating the sulfonation mixture, the Lewis acid can be removed together with the sulfuric acid.
摘要翻译： 含有至少一个能够被磺化的芳族基团的芳基膦（即单 - ，二 - ，寡 - 和多膦）的磺化在路易斯酸存在下在0-80℃下进行。该方法避免了 副反应，特别是氧化膦的形成。 在处理磺化混合物时，路易斯酸可与硫酸一起除去。
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公开(公告)号：US5466644A
公开(公告)日：1995-11-14
申请号：US378861
申请日：1995-01-19
IPC分类号： B01J27/185 , B01J27/28 , B01J31/24 , B01J31/40 , B01J38/48 , C07B61/00 , C07C27/20 , C07C27/22 , C07C45/50 , C07C45/85 , C07C47/02 , B01J38/62
CPC分类号： B01J31/4046 , B01J31/20 , B01J31/2404 , B01J31/2447 , C07C45/50 , C07C45/85 , B01J2231/321 , B01J2531/822 , B01J2531/96 , Y02P20/584
摘要： A process for regenerating a water-soluble hydroformylation catalyst system comprising a coupler rhodium hydrogen-carbonyl complex of rhodium and compounds of the formula ##STR1## wherein Ar.sup.1 and Ar.sup.2 and Ar.sup.3 are individually phenyl or naphthyl, Y.sup.1, Y.sup.2 and Y.sup.3 are individually selected from the group consisting of alkyl and alkoxy of 1 to 4 carbon atoms, halogen, --OH, --CN, --NO.sub.2 and R.sup.1 R.sup.2 N--, R.sup.1 and R.sup.2 are individually alkyl of 1 to 4 carbon atoms, X.sup.1, X.sup.2 and X.sup.3 are individually carboxylate (--COO.sup.-) or sulfonate (--SO.sub.3.sup.-), m.sub.1, m.sub.2 and m.sub.3 are individually integers of 0 to 3, at least one of m.sub.1, m.sub.2 or m.sub.3 being equal to or greater than 1, and n.sub.1, n.sub.2 and n.sub.3 are individually integers of 0 to 5 and if appropriate in excess comprising adding maleic acid, fumaric acid or olefinically unsaturated compounds of formula ##STR2## wherein X is selected from the group consisting of O, S, -- ##STR3## or ##STR4## and R.sup.3, R.sup.4 and R.sup.5 are individually hydrogen, or alkyl or aryl to an aqueous solution of the catalyst system in an amount sufficient to remove sulfonated or carboxylated alkyl-arylphosphanes.
摘要翻译： 一种再生水溶性加氢甲酰化催化剂体系的方法，其包含铑的偶合铑氢 - 羰基络合物和其中Ar1和Ar2和Ar3各自独立地为苯基或萘基，Y1，Y2和Y3的式I化合物的化合物， 由1-4个碳原子的烷基和烷氧基组成的组，卤素，-OH，-CN，-NO 2和R 1 R 2 N - ，R 1和R 2分别是1至4个碳原子的烷基，X 1，X 2和X 3分别是羧酸酯 （-COO-）或磺酸盐（-SO3-），m1，m2和m3分别为0-3的整数，m1，m2或m3中的至少一个等于或大于1，n1，n2和n3分别为 单独的整数为0至5，如果适当，过量包括加入马来酸，富马酸或烯属不饱和的式II化合物，其中X选自O，S， - IMAGE或IMAGE，和 R3，R4和R5分别是氢，或烷基或芳基与催化剂的水溶液 t系统，其量足以除去磺化或羧化的烷基 - 芳基磷烷。
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7.发明授权Sulfonated phosphines, processes for their preparation, and use thereof as constituents of catalyst systems 失效磺化膦，其制备方法及其作为催化剂体系的组分的用途
公开(公告)号：US5663426A
公开(公告)日：1997-09-02
申请号：US538190
申请日：1995-10-02
IPC分类号： C07F9/50 , C07C309/30 , C07C309/29 , C07C309/32
CPC分类号： C07F9/5022
摘要： Sulfonated phosphines of the formula ##STR1## in which R is cyclohexyl or alkyl having 1 to 4 carbon atoms, M is hydrogen, alkyl substituted ammonium, aryl substituted-ammonium, monovalent metal, or the chemical equivalent of a polyvalent metal, x is 1, 2, or 3 and n is 0 or 1. These compounds are obtained by sulfonation of the non-sulfonated parent substances with oleum or an anhydrous mixture of sulfuric acid and orthoboric acid.
摘要翻译： 其中R是环己基或具有1-4个碳原子的烷基的磺酰化膦，M是氢，烷基取代的铵，芳基取代的铵，一价金属或多价金属的化学当量，x是1 ，2或3，n为0或1.这些化合物通过用发烟硫酸或硫酸和原硼酸的无水混合物磺化非磺化母体物质而获得。
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8.发明授权5H-phenyl-3,13-disulfonatodibenzo-phosphole and a process for its preparation 失效5H-苯基-3,13-二磺基二苯并菲磷及其制备方法
公开(公告)号：US5637762A
公开(公告)日：1997-06-10
申请号：US538012
申请日：1995-10-02
IPC分类号： C07F9/6568 , C07F9/50
CPC分类号： C07F9/65683
摘要： 5H-phenyl-3,13-disulfonatodibenzophosphole and a process for its preparation.
摘要翻译： 5H-苯基-3,13-二磺基二苯并磷酸盐孔及其制备方法。
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9.发明授权Sulfonated phosphines, processes for their preparation, and use thereof as constituents of catalyst systems 失效磺化膦，其制备方法及其作为催化剂体系的组分的用途
公开(公告)号：US5780674A
公开(公告)日：1998-07-14
申请号：US801150
申请日：1997-02-18
CPC分类号： C07F9/5022
摘要： Sulfonated phosphines of the formula ##STR1## in which R is cyclohexyl or alkyl having 1 to 4 carbon atoms, M is hydrogen, alkyl substituted ammonium, aryl substituted-ammonium, monovalent metal, or the chemical equivalent of a polyvalent metal, x is 1, 2, or 3 and n is 0 or 1. These compounds are obtained by sulfonation of the non-sulfonated parent substances with oleum or an anhydrous mixture of sulfuric acid and orthoboric acid.
摘要翻译： 其中R是环己基或具有1-4个碳原子的烷基的磺酰化膦，M是氢，烷基取代的铵，芳基取代的铵，一价金属或多价金属的化学当量，x是1 ，2或3，n为0或1.这些化合物通过用发烟硫酸或硫酸和原硼酸的无水混合物磺化非磺化母体物质而获得。
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公开(公告)号：US5684181A
公开(公告)日：1997-11-04
申请号：US537357
申请日：1995-10-02
IPC分类号： C07F9/50
CPC分类号： C07F9/5054
摘要： The sulfonation of arylphosphines, which contain at least one aromatic radical which can be sulfonated, is carried out with an anhydrous mixture of sulfuric acid and orthoboric acid. By choosing the appropriate reaction temperature, the process allows selective introduction of the desired number of sulfonic acid radicals into the phosphine molecule and avoids the formation of phosphine oxides. When separating the sulfonation mixture, the orthoboric acid can be separated off together with the sulfuric acid.
摘要翻译： 含有至少一个可被磺化的芳族基团的芳基膦的磺化用硫酸和原硼酸的无水混合物进行。 通过选择合适的反应温度，该方法允许选择性地将所需数量的磺酸基团引入到膦分子中，并避免形成氧化膦。 当分离磺化混合物时，原硼酸可以与硫酸一起分离出来。
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