发明授权
- 专利标题: Preparation of tetrahydropyran-4-carboxylic acid and esters thereof
- 专利标题(中): 四氢吡喃-4-羧酸及其酯的制备
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申请号: US110219申请日: 1993-08-23
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公开(公告)号: US5371246A公开(公告)日: 1994-12-06
- 发明人: Dirk Borchers , Rolf Fischer , Norbert Goetz , Thomas Kuekenhoehner , Werner Schnurr
- 申请人: Dirk Borchers , Rolf Fischer , Norbert Goetz , Thomas Kuekenhoehner , Werner Schnurr
- 申请人地址: DEX Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DEX Ludwigshafen
- 优先权: DEX4228669 19920828
- 主分类号: B01J21/04
- IPC分类号: B01J21/04 ; C07B61/00 ; C07D309/08 ; C07D309/06
摘要:
A process for the preparation of tetrahydropyran-4-carboxylic acid and esters thereof of the general formula I ##STR1## in which R.sup.1 denotes hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.5 -C.sub.8 cycloalkyl, or aryl by the reaction of a dihydro-2(3H)furanone of the general formula II ##STR2## in which R.sup.2 denotes hydrogen, C.sub.1 -C.sub.6 alkyl, or --CO--R.sup.3 andR.sup.3 denotes hydrogen or C.sub.1 -C.sub.6 alkyl, with water or an alcohol of the general formula IIIR.sup.1 --OH (III),in whichR.sup.1 has the aforementioned meaning,at temperatures ranging from 200.degree. to 350.degree. C. in the presence of a heterogenous acid catalyst, in which use is made of a fixed heterogenous acid catalyst.
公开/授权文献
- USD430419S Chair 公开/授权日:2000-09-05
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