发明授权
- 专利标题: Process for producing methyl methacrylate
- 专利标题(中): 生产甲基丙烯酸甲酯的方法
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申请号: US135066申请日: 1993-10-12
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公开(公告)号: US5371273A公开(公告)日: 1994-12-06
- 发明人: Yoshikazu Shima , Takafumi Abe , Hirofumi Higuchi
- 申请人: Yoshikazu Shima , Takafumi Abe , Hirofumi Higuchi
- 申请人地址: JPX Tokyo
- 专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX4-305542 19921116
- 主分类号: B01J29/08
- IPC分类号: B01J29/08 ; C07B61/00 ; C07C67/327 ; C07C69/54 ; C07C67/00
摘要:
There is disclosed a process for producing methyl methacrylate through gas-phase catalytic reaction of methyl .alpha.-hydroxyisobutyrate which comprises feeding methanol in an amount by weight of 0.1 to 3.0 times the methyl .alpha.-hydroxyisobutyrate in a reactor along therewith and proceeding with the reaction at a reaction temperature in the range of 230.degree. to 300.degree. C. by the use of a transition-type synthetic faujasite zeolite having a specific lattice constant and a specific Na content (Na/Al) as the catalyst. The process is capable of stably producing the objective product having excellent quality in high yield for a long period of time while preventing the problems of early deterioration of the catalyst and coloring of reaction product.
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