发明授权
- 专利标题: Process for producing grafted polycarbonate resin
- 专利标题(中): 生产接枝聚碳酸酯树脂的方法
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申请号: US91756申请日: 1993-07-15
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公开(公告)号: US5426159A公开(公告)日: 1995-06-20
- 发明人: Toshikazu Umemura
- 申请人: Toshikazu Umemura
- 申请人地址: JPX Tokyo
- 专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX3-182933 19910627
- 主分类号: C08F290/06
- IPC分类号: C08F290/06 ; C08F283/02 ; C08L69/00
摘要:
Disclosed is a process for producing a grafted polycarbonate resin for optical use, which comprises adding to an aqueous suspension of an aromatic polycarbonate resin having radical-polymerizable unsaturated terminal group on a molecule wherein the aromatic polycarbonate resin has an average particle diameter of 0.1 to 5 mm and an apparent density of 0.2 to 0.9 g/cm.sup.3, a vinyl monomer and a radical-polymerization initiator, heating the aqueous suspension at a lower temperature by 5.degree. C. to 20.degree. C. than the decomposition temperature for a half-life period of 10 hours of the radical-polymerization initiator, thereby impregnating the polycarbonate resin with the vinyl monomer and the radical-polymerization initiator, then elevating the temperature to the range of from a lower temperature by 50.degree. C. to a higher temperature by 30.degree. C. than the decomposition temperature for a half-life period of 10 hours of the radical-polymerization initiator, thereby conducting a graft-polymerization reaction to obtain 90% by weight or more of conversion of vinyl monomer.
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