A printing sheet of the type which is used in a thermal transfer system, the printing sheet comprising a support and a dye receiving layer formed thereon, the dye receiving layer including a polymer containing isocyanate group, the polymer having polysiloxane unit and urea unit. The isocyanate group-containing polymer is selected from a reaction product between a multifunctional polyisocyanate compound and amino-modified silicone, or a reaction product between a multifunctional polyisocyanate compound and alcohol-modified silicone or carboxyl-modified silicone and an amine compound or water. According to the present invention, both the writing characteristic and anti-sebaceous characteristic on an image surface are improved simultaneously while basic characteristics such as printing sheet sensitivity, image preservative stability, and so on, are satisfied.