发明授权
- 专利标题: Supported metallocene catalysts for the production of polyolefins
- 专利标题(中): 用于生产聚烯烃的负载型茂金属催化剂
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申请号: US161849申请日: 1993-12-06
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公开(公告)号: US5498582A公开(公告)日: 1996-03-12
- 发明人: Michael J. Krause , Frederick Y. Lo , Steven M. Chranowski
- 申请人: Michael J. Krause , Frederick Y. Lo , Steven M. Chranowski
- 申请人地址: VA Fairfax
- 专利权人: Mobil Oil Corporation
- 当前专利权人: Mobil Oil Corporation
- 当前专利权人地址: VA Fairfax
- 主分类号: C08F4/642
- IPC分类号: C08F4/642 ; B01J31/22 ; C08F4/02 ; C08F4/64 ; C08F4/659 ; C08F4/6592 ; C08F10/00 ; C08F10/02 ; B01J31/14 ; B01J37/02
摘要:
A catalyst precursor is formed by providing in slurry: (1) a carrier, which is porous and in the form of particles, or spheres, preferably particles of a crosslinked polymer, having a particle diameter of about 1 to about 300 microns, a porosity of about 0.001 to about 10 cc/gm, and a surface area of about 1 to about 1,000 m.sup.2 /gm; (2) a metallocene complex having an empirical formulaCp.sub.m MA.sub.n B.sub.pin which Cp is an unsubstituted or substituted cyclopentadienyl group, M is zirconium, titanium, or hafnium; m is 1, 2, or 3 and each of A and B is a halogen atom, hydrogen or an alkyl group, and (3) an anion forming reagent comprising either a borate complex or a borane. An alkyl aluminum compound is used in conjunction with the catalyst as either a cocatalyst or an impurity scavenger.
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