发明授权
- 专利标题: Mixtures of alkylated aromatic amines and phenothiazines
- 专利标题(中): 烷基化芳香胺和吩噻嗪的混合物
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申请号: US359978申请日: 1994-12-20
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公开(公告)号: US5503759A公开(公告)日: 1996-04-02
- 发明人: Samuel Evans , Stephan Allenbach
- 申请人: Samuel Evans , Stephan Allenbach
- 申请人地址: NY Tarrytown
- 专利权人: Ciba-Geigy Corporation
- 当前专利权人: Ciba-Geigy Corporation
- 当前专利权人地址: NY Tarrytown
- 优先权: CHX3845/93 19931223
- 主分类号: C07D279/36
- IPC分类号: C07D279/36 ; C07C211/54 ; C07C211/55 ; C07C211/58 ; C07D279/20 ; C08K5/1545 ; C09K15/18 ; C09K15/30 ; C10M159/12 ; C10N30/04 ; C10N40/08 ; C10N40/20 ; C10M135/36 ; C08K5/34
摘要:
The invention relates to reaction products suitable as antioxidants which are substantially liquid at room temperature and which are obtained by the reaction of olefins with mixtures of diphenylamines and phenothiazines which may be alkylated. These products are obtainable by reacting an olefin of formulaR.sub.1 R.sub.2 C.dbd.CHR.sub.3 (I)with a mixture of compounds of formulae II and III ##STR1## in the presence of an acid catalyst, wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.25 alkyl or phenyl,R.sub.2 is C.sub.1 -C.sub.25 alkyl, benzyl or phenyl,R.sub.3 is hydrogen or C.sub.1 -C.sub.12 alkyl,R.sub.4, R*.sub.4, R.sub.5 and R*.sub.5 are each independently of one another hydrogen, C.sub.1 -C.sub.25 alkyl, C.sub.5 -C.sub.12 cycloalkyl, benzyl, .alpha.-methylbenzyl or .alpha.,.alpha.-dimethylbenzyl, and R.sub.6 and R*.sub.6 are each independently of the other hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.4 alkenyl, benzyl or a radical of formula --CH(R.sub.9)--CH(R.sub.10)--S--R.sub.11, andR.sub.7 and R.sub.8 are hydrogen, or together form a divalent group ##STR2## R.sub.9 and R.sub.10 are each independently of the other hydrogen, phenyl or C.sub.1 -C.sub.12 alkyl,R.sub.11 is C.sub.4 -C.sub.18 alkyl, phenyl or --(CH.sub.2).sub.a --CO--OR.sub.12,a is 1 or 2, andR.sub.12 is C.sub.1 -C.sub.18 alkyl.
公开/授权文献
- US4988464A Method for producing powder by gas atomization 公开/授权日:1991-01-29
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