发明授权
- 专利标题: Process for producing high stiffness polypropylene
- 专利标题(中): 高刚性聚丙烯生产工艺
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申请号: US545232申请日: 1995-10-19
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公开(公告)号: US5532325A公开(公告)日: 1996-07-02
- 发明人: Takahiro Oka , Hiromasa Chiba
- 申请人: Takahiro Oka , Hiromasa Chiba
- 申请人地址: JPX Osaka
- 专利权人: Chisso Corporation
- 当前专利权人: Chisso Corporation
- 当前专利权人地址: JPX Osaka
- 优先权: JPX63-82597 19880404
- 主分类号: C08F4/64
- IPC分类号: C08F4/64 ; C08F4/60 ; C08F4/649 ; C08F10/00 ; C08F10/06 ; C08F110/06 ; C08F4/655
摘要:
A process for producing polypropylene is provided which comprises polymerizing propylene in multiple stages, in the presence of a catalyst which is prepared by reacting a first organoaluminum compound (i), or a reaction product (vi) formed between the first organoaluminum compound (i) and an electron donor (a), with titanium tetrachloride (c) to obtain a first solid product (ii), reacting the resulting first solid product (ii) with the electron donor (a) and an electron acceptor (b) to obtain a second solid product (iii), and combining the resulting second solid product (iii) with a second organoaluminum compound (iv) and an aromatic carboxylic acid ester (v) at a molar ratio of the aromatic carboxylic acid ester to the second solid product (v/iii molar ratio) of from 0.1 to 10.0, in such a manner that from 10 to 90% by weight of the total polymer is produced in a first stage and the balance of the total polymer is produced in a second and any subsequent stages with the v/iii molar ratio of the catalyst being made higher in the second and any subsequent stages than that in the catalyst used in the first stage by adding the aromatic carboxylic acid ester (v) to the polymerization system so as to give 1.ltoreq.v/iii molar ratio.ltoreq.10, while controlling the melt flow rate (MFR) of a polymer portion produced in each of the first and any subsequent stages so as to satisfy the relationships:0.5
公开/授权文献
- US4538050A Baker's oven 公开/授权日:1985-08-27
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