发明授权
US5573673A Hydrous composite cerium-phosphorus oxide for immobilization of
strontium ions in solution
失效
用于在溶液中固定锶离子的水性复合铈 - 磷氧化物
- 专利标题: Hydrous composite cerium-phosphorus oxide for immobilization of strontium ions in solution
- 专利标题(中): 用于在溶液中固定锶离子的水性复合铈 - 磷氧化物
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申请号: US404097申请日: 1995-03-14
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公开(公告)号: US5573673A公开(公告)日: 1996-11-12
- 发明人: Hiromichi Hayashi , Yoshio Onodera , Takashi Iwasaki , Osamu Itabashi , Kazuo Torii
- 申请人: Hiromichi Hayashi , Yoshio Onodera , Takashi Iwasaki , Osamu Itabashi , Kazuo Torii
- 申请人地址: JPX
- 专利权人: Agency of Industrial Science and Technology
- 当前专利权人: Agency of Industrial Science and Technology
- 当前专利权人地址: JPX
- 优先权: JPX6-117621 19940506
- 主分类号: B01D15/00
- IPC分类号: B01D15/00 ; B01J20/02 ; C01F11/00 ; G21F9/12 ; C01F17/00 ; C02F1/42
摘要:
Disclosed is a novel hydrous composite oxide of cerium (IV) and phosphorus characterized by the specified chemical composition and the unique X-ray diffractometric pattern, which is useful as an adsorbent or immobilizing agent of strontium ions in an aqueous solution such as radioactive wastes from atomic power plants. The composite oxide prepared by the precipitation reaction of a Ce (IV) salt in an aqueous solution and phosphoric acid can be imparted with an increased adsorption capacity for strontium ions when the precipitates are heat-treated under hydrothermal conditions at up to 300.degree. C. Immobilization of strontium ions adsorbed on the adsorbent can be more complete when the adsorbent bearing strontium ions is dried and subjected to a heat treatment at a temperature of 200.degree. C. or higher.