发明授权
US5599848A Preparation, intermediates for the preparation and the use of a mixture
of dodecdienol isomers
失效
制备，中间体制备和使用十二二烯醇异构体的混合物
- 专利标题： Preparation, intermediates for the preparation and the use of a mixture of dodecdienol isomers
- 专利标题（中）： 制备，中间体制备和使用十二二烯醇异构体的混合物
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申请号： US512259申请日： 1995-08-07
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公开(公告)号： US5599848A公开(公告)日： 1997-02-04
- 发明人: Ulrich Klein , Ulrich Neumann , Wolfgang Mackenroth , Guenter Renz , Wolfgang Krieg , Christiane Mackenroth , Ernst Buschmann , Jacobus J. DeKramer , Roland Milli
- 申请人： Ulrich Klein , Ulrich Neumann , Wolfgang Mackenroth , Guenter Renz , Wolfgang Krieg , Christiane Mackenroth , Ernst Buschmann , Jacobus J. DeKramer , Roland Milli
- 申请人地址： DEX Ludwigshafen
- 专利权人： BASF Aktiengesellschaft
- 当前专利权人： BASF Aktiengesellschaft
- 当前专利权人地址： DEX Ludwigshafen
- 优先权： DEX4135064.2 19911024
- 主分类号： C07C33/02
- IPC分类号： C07C33/02 ; C07C43/313 ; C07C43/315 ; A01N31/02
摘要：
A process for preparing a mixture of 8E,10E-dodecadienol (Ia), 8E,10Z-dodecadienol (Ib), 8Z,10E-dodecadienol (Ic) and 8Z,10Z-dodecadienol (Id),H.sub.3 C--CH.dbd.CH--CH.dbd.CH--(CH.sub.2).sub.6 --CH.sub.2 --OH(8E,10E=Ia)(8E,10Z=Ib)(8Z,10E=Ic)(8Z,10Z=Id)starting from 1,8-octanediol (II) which is converted with a halogenating agent into (III)Hal-CH.sub.2 --(CH.sub.2).sub.6 --CH.sub.2 --OH (III)where (III) is subsequently reacted with (IV),H.sub.2 C.dbd.CH--O--R (IV)to give (V)Hal-CH.sub.2 --(CH.sub.2).sub.6 --CH.sub.2 --O--CH(CH.sub.3)--OR(V),(V) is converted in the presence of magnesium and crotonaldehyde into (VI)H.sub.3 C--CH.dbd.CH--CH(OH)--(CH.sub.2).sub.8 --O--CH(CH.sub.3)--OR(VI)and the protective group R and the hydroxyl group are simultaneously eliminated from (VI) in the presence of acid, novel intermediates for this process, and methods for controlling the codling moth Cydia pomonella by interfering with mating using this mixture are described.
公开/授权文献
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