发明授权
US5618879A Aqueous dispersions of functional graft polyorganosiloxanes and curable silicone compositions comprised thereof 失效
功能性接枝聚有机硅氧烷的水性分散体及其可固化的聚硅氧烷组合物

Aqueous dispersions of functional graft polyorganosiloxanes and curable
silicone compositions comprised thereof
摘要:
Stable reactive aqueous dispersions of functional graft polyorganosiloxanes, well suited for formulation into curable silicone compositions useful in the production of release- and other coatings and paints, comprise the polymerizate of at least one ethylenically unsaturated monomer with a functional polyorganosiloxane which comprises identical or different recurring structural units of formula (I):R.sub.a Y.sub.b X.sub.c SiO.sub.(4-a-b-c)/2 (I)in which the radicals R, which may be identical or different, are each a C.sub.1 -C.sub.18 alkyl radical, a C.sub.2 -C.sub.20 alkenyl radical, or a C.sub.6 -C.sub.12 aryl or aralkyl radical, or halogen-substituted such radical; the radicals X, which may be identical or different, are each a hydrogen atom or a reactive functional group bonded to a silicon atom via an Si-C or Si-O-C linkage; the radicals Y, which may be identical or different, are each an ethylenically unsaturated hydrocarbon radical optionally comprising one or more of the heteroelements O and/or N, and bonded to a silicon atom of the structural unit of formula (I) via an Si-C linkage and reactive with said at least one ethylenically unsaturated monomer; a, b and c are each equal to 0, 1, 2 or 3; and a+b+c=0, 1, 2 or 3; with the proviso that the number of SiO.sub.4/2 units is less than 30 mol % and the number of structural units of formula (I) in which the silicon atom is substituted by a functional group X and/or a radical Y is such that the polyorganosiloxane comprises (i) at least 5 milliequivalents, preferably from 10 to 500 milliequivalents, of X functional groups per 100 grams of polyorganosiloxane of formula (I) and (ii) at least 5 milliequivalents, preferably from 10 to 500 milliequivalents, of Y radicals per 100 grams of polyorganosiloxane of formula (I).
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