发明授权
US5633413A Continuous process for the production of vinylidene chloride telomers
失效
用于生产偏二氯乙烯调节剂的连续方法
- 专利标题: Continuous process for the production of vinylidene chloride telomers
- 专利标题(中): 用于生产偏二氯乙烯调节剂的连续方法
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申请号: US512575申请日: 1995-08-08
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公开(公告)号: US5633413A公开(公告)日: 1997-05-27
- 发明人: Michael Van Der Puy , Timothy R. Demmin , David E. Bradley
- 申请人: Michael Van Der Puy , Timothy R. Demmin , David E. Bradley
- 申请人地址: NJ Morris County
- 专利权人: AlliedSignal Inc.
- 当前专利权人: AlliedSignal Inc.
- 当前专利权人地址: NJ Morris County
- 主分类号: C07C17/278
- IPC分类号: C07C17/278 ; C07C17/08 ; C07C17/266 ; C07C17/275
摘要:
A process for the continuous production of telomers CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.n Cl where n=1-3 (Formula I) by the continuous reaction of CCl.sub.4 and vinylidene chloride in the presence of a solvent and a catalyst. The reaction to form CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl proceeds at a reaction rate constant k.sub.1. If n=1, CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl is continuously removed from the reactor. If n=2, the removed CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl reacts similarly with CCl.sub.4 and CH.sub.2 .dbd.CCl.sub.2 in a second reactor to form and remove CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.2 Cl under conditions to have a reaction rate constant k.sub.2, wherein the ratio of the molar amounts of CCl.sub.4 to CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl reacted is greater than the ratio k.sub.2 /k.sub.1. If n=3, the removed CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.2 Cl similarly reacts in a third reactor with CCl.sub.4 and CH.sub.2 .dbd.CCl.sub.2 to form CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.3 Cl under conditions to have a reaction rate constant k.sub.3, wherein the ratio of the molar amounts of CCl.sub.4 to CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.2 Cl reacted is greater than the ratio k.sub.3 /k.sub.2.
公开/授权文献
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