- 专利标题: One-step synthesis of methyl t-butyl ether from t-butanol using .beta.-zeolite catalysts modified with lithium plus rare earths
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申请号: US346449申请日: 1994-11-29
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公开(公告)号: US5716896A公开(公告)日: 1998-02-10
- 发明人: John Frederick Knifton , Pei-Shing Eugene Dai
- 申请人: John Frederick Knifton , Pei-Shing Eugene Dai
- 专利权人: Knifton; John Frederick,Dai; Pei-Shing Eugene
- 当前专利权人: Knifton; John Frederick,Dai; Pei-Shing Eugene
- 主分类号: B01J29/70
- IPC分类号: B01J29/70 ; C07B61/00 ; C07C41/09 ; C07C43/04 ; B01J31/00
摘要:
Disclosed is a method for producing alkyl tertiary alkyl ethers which comprises reacting t-butanol with an alkanol in the presence of a catalyst which exhibits extended life comprising .beta.-zeolite modified with one or more metals selected from the group consisting of Group IA and Group IIIB of the Periodic Table and continuously contacting said alkanol and t-butanol in a molar amount from about 10:1 to 1:10 over said zeolite catalyst at a temperature of about 20.degree. C. to about 250.degree. C. and a pressure of about atmospheric to about 1000 psig.
公开/授权文献
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