发明授权
US5716914A Alkaline earth metal hydrocarbyl phenates, their sulphurized derivatives, their production and use thereof 失效
碱土金属烃基酚盐,其硫化衍生物,其生产和用途

Alkaline earth metal hydrocarbyl phenates, their sulphurized
derivatives, their production and use thereof
摘要:
Process for producing an additive concentrate having a viscosity of less than 1000 cSt at 100 EC, by reacting at elevated temperature and in the presence of an inorganic halide or calcium acetate catalyst (A) either (i) a hydrocarbyl phenol or (ii) a hydrocarbyl phenol and sulphur, (B) an alkaline earth metal base added in either a single addition or in a plurality of additions during the reaction, (C) either a polyhydric alcohol having from 2 to 4 carbon atoms, a di- or tri- C.sub.2 to C.sub.4 glycol, an alkylene glycol alkyl ether or a polyalkylene glycol alkyl ether, (D) a lubricating oil, (E) carbon dioxide added subsequent to the, or each, addition of compound (B), and (F) sufficient to provide from 12 to less than 40% by weight based on the weight of the concentrate of either (i) a carboxylic acid having the formula RCH(R')COOH, wherein R is a C.sub.10 to C.sub.24 alkyl or alkenyl group and R is either hydrogen, a C.sub.1 to C.sub.4 alkyl group or a --CH.sub.2 --COOH group, or an anhydride, acid chloride or ester thereof or (ii) a di- or polycarboxylic acid containing from 36 to 100 carbon atoms or an anhydride, acid chloride or ester thereof, the weight ratios of components (A) to (F) being such as to produce a concentrate having a TBN greater than 350.
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