发明授权
- 专利标题: Preparation of amines from olefins over zeolites of the type SSZ-37
- 专利标题(中): 通过SSZ-37型沸石从烯烃制备胺
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申请号: US760296申请日: 1996-12-04
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公开(公告)号: US5739405A公开(公告)日: 1998-04-14
- 发明人: Karsten Eller , Rudolf Kummer , Peter Stops
- 申请人: Karsten Eller , Rudolf Kummer , Peter Stops
- 申请人地址: DEX Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DEX Ludwigshafen
- 优先权: DEX19545876.1 19951208
- 主分类号: B01J29/06
- IPC分类号: B01J29/06 ; C07B61/00 ; C07C209/60 ; C07C211/03 ; C07C211/07 ; C07C211/17 ; C07C211/21 ; C07C211/25 ; C07C211/26 ; C07C211/35 ; C07C211/40 ; C07C211/45
摘要:
A process for the preparation of amines of the general formula I ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 denote hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkenyl, C.sub.2 -C.sub.20 alkynyl, C.sub.3 -C.sub.20 cycloalkyl, C.sub.4 -C.sub.20 alkylcycloalkyl, C.sub.4 -C.sub.20 cycloalkylalkyl, aryl, C.sub.7 -C.sub.20 alkylaryl, or C.sub.7 -C.sub.20 aralkyl, R.sup.1 and R.sup.2 together denote a saturated or unsaturated C.sub.3 -C.sub.9 alkylene dichain and R.sup.3 or R.sup.5 denotes C.sub.21 -C.sub.200 alkyl, C.sub.21 -C.sub.200 alkenyl or they together form a C.sub.2 -C.sub.12 alkylene dichain, by the reaction of olefins of the general formula II ##STR2## in which R.sup.3, R.sup.4, R.sup.5, and R.sup.6 have the above meanings, with ammonia or primary or secondary amines of the general formula III ##STR3## in which R.sup.1 and R.sup.2 have the above meanings, at temperatures ranging from 200.degree. to 350.degree. C. and pressures ranging from 100 to 300 bar in the presence of a heterogeneous catalyst, wherein the heterogeneous catalyst used is a zeolite of the type SSZ-37.
公开/授权文献
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