发明授权
- 专利标题: Metallocene compound
- 专利标题(中): 茂金属化合物
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申请号: US681636申请日: 1996-07-29
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公开(公告)号: US5767300A公开(公告)日: 1998-06-16
- 发明人: Michael Aulbach , Hans-Friedrich Herrmann , Dieter Bilda , Carsten Bingel
- 申请人: Michael Aulbach , Hans-Friedrich Herrmann , Dieter Bilda , Carsten Bingel
- 申请人地址: DEX Ludwigshafen
- 专利权人: Targor GmbH
- 当前专利权人: Targor GmbH
- 当前专利权人地址: DEX Ludwigshafen
- 优先权: DEX19527652.3 19950728
- 主分类号: B01J31/22
- IPC分类号: B01J31/22 ; C07F17/00 ; C08F4/60 ; C08F4/639 ; C08F4/6392 ; C08F4/642 ; C08F4/643 ; C08F4/646 ; C08F4/6592 ; C08F4/68 ; C08F4/69 ; C08F10/00 ; C07F7/02 ; C07F9/00
摘要:
The present invention relates to a metallocene compound of the formula I which is suitable for olefin polymerization ##STR1## where M is a metal of group IVb, Vb or VIb of the Periodic Table. X are each a hydrogen atom, a halogen atom or a C.sub.1 -C.sub.40 -radical OR.sup.4 or NR.sup.4.sub.2, where R.sup.4 are a C.sub.1 -C.sub.20 hydrocarbon radical m and p are 1, 2 or 3, n is 1 or 2, L each a .pi. ligand which coordinates to the central atom M, M.sup.2 are each a silicon atom, a germanium atom or a tin atom, R.sup.1 are a C.sub.1 -C.sub.20 -radical, R.sup.2 are a C.sub.1 -C.sub.20 -radical or a .pi. ligand which coordinates to the central atom M, A are each a bidentate C.sub.1 -C.sub.40 -hydrocarbon group, Z are each a boron atom, a silicon atom, a germanium atom or a tin atom, R.sup.3 are each a hydrogen atom or a C.sub.1 -C.sub.20 -radical, o is zero, 1 or 2, Hal are each a halogen atom, and where n is 1 if R.sup.2 is a .pi. ligand which coordinates to the central atom M and n is 2 if R.sup.2 is a C.sub.1 -C.sub.20 -radical.
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