发明授权
US5773671A Process for purifying 1,1-dichloro-2,2,2-trifluoroethane and 1-chloro-1,2,2,2-tetrafluoroethane 失效
1,1-二氯-2,2,2-三氟乙烷和1-氯-1,2,2,2-四氟乙烷的纯化方法

  • 专利标题: Process for purifying 1,1-dichloro-2,2,2-trifluoroethane and 1-chloro-1,2,2,2-tetrafluoroethane
  • 专利标题(中): 1,1-二氯-2,2,2-三氟乙烷和1-氯-1,2,2,2-四氟乙烷的纯化方法
  • 申请号: US768338
    申请日: 1996-12-17
  • 公开(公告)号: US5773671A
    公开(公告)日: 1998-06-30
  • 发明人: Hsueh Sung Tung
  • 申请人: Hsueh Sung Tung
  • 申请人地址: NJ Morristown
  • 专利权人: Allied Signal
  • 当前专利权人: Allied Signal
  • 当前专利权人地址: NJ Morristown
  • 主分类号: B01J23/26
  • IPC分类号: B01J23/26 C07C17/395 C07C17/38
Process for purifying 1,1-dichloro-2,2,2-trifluoroethane and
1-chloro-1,2,2,2-tetrafluoroethane
摘要:
The invention relates to a novel process for purifying HCFC-123 and HCFC-124 comprising: (a) reacting a fluorination reaction product comprising HCFC-123 and HCFC-123a and/or HCFC-124 and HCFC-124a wherein at least one of said HCFC-123a or HCFC-124a is present in an amount not less than 5 weight percent relative to HCFC-123 or HCFC-124 respectively in the product with anhydrous HF in the presence of a fluorination catalyst under conditions such that the amount of HCFC-123a and/or HCFC-124a relative to HCFC-123 and/or HCFC-124 respectively in the product is reduced to less than 5 weight percent. The pure product (i.e., HCFC-123 or HCFC-124) may be used in a variety of applications including solvent, refrigerant, sterilant gas and blowing agent applications.
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