发明授权
US5807948A Vulcanizable rubber composition containing
ehtylene-.alpha.-olefin-nonconjugated polyene random copolymer
失效
含有乙烯-α-烯烃 - 非共轭多烯无规共聚物的可硫化橡胶组合物
- 专利标题: Vulcanizable rubber composition containing ehtylene-.alpha.-olefin-nonconjugated polyene random copolymer
- 专利标题(中): 含有乙烯-α-烯烃 - 非共轭多烯无规共聚物的可硫化橡胶组合物
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申请号: US783238申请日: 1997-01-14
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公开(公告)号: US5807948A公开(公告)日: 1998-09-15
- 发明人: Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Hidenari Nakahama , Tetsuo Tojo
- 申请人: Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Hidenari Nakahama , Tetsuo Tojo
- 申请人地址: JPX Tokyo
- 专利权人: Mitsui Petrochemical Industries, Ltd.
- 当前专利权人: Mitsui Petrochemical Industries, Ltd.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX6-316951 19941220; JPX7-059289 19950317; JPX7-318400 19951206
- 主分类号: C08F4/64
- IPC分类号: C08F4/64 ; C08F4/659 ; C08F4/6592 ; C08F210/18 ; C08L23/16 ; C08F236/20
摘要:
Disclosed is a process for preparing an ethylene-.alpha.-olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an .alpha.-olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the .alpha.-olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 �(a)/(b)!, (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity (.eta.) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T.alpha..beta. to T.alpha..alpha. in the .sup.13 C-NMR spectrum, T.alpha..beta./T.alpha..alpha., is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50.degree. C., and (vii) the ratio g.eta.* of the intrinsic viscosity (.eta.) of this copolymer defined above to the intrinsic viscosity (.eta.).sub.blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, (.eta.)/(.eta.).sub.blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.
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