发明授权
- 专利标题： Preparation of epoxides by means of aromatic peroxycarboxylic acids
- 专利标题（中）： 通过芳族过氧羧酸制备环氧化物
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申请号： US875607申请日： 1997-08-05
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公开(公告)号： US5808114A公开(公告)日： 1998-09-15
- 发明人: Joaquim Henrique Teles , Werner Schnurr , Rolf Fischer , Norbert Rieber , Michael Schulz
- 申请人： Joaquim Henrique Teles , Werner Schnurr , Rolf Fischer , Norbert Rieber , Michael Schulz
- 申请人地址： DEX Ludwigshafen
- 专利权人： BASF Aktiengesellschaft
- 当前专利权人： BASF Aktiengesellschaft
- 当前专利权人地址： DEX Ludwigshafen
- 优先权： DEX19505858.5 19950221
- 主分类号： C07C45/41
- IPC分类号： C07C45/41 ; C07D301/14 ; C07D303/04
摘要：
Preparation of epoxides from olefins by means of aromatic peroxycarboxylic acids comprises a step A of epoxidizing the olefin and removing the resulting aromatic carboxylic acid from the epoxide, a step B of catalytically hydrogenating the removed aromatic carboxylic acid to the corresponding aromatic aldehyde, and a step C of oxidizing this aldehyde with oxygen or an oxygen-containing gas mixture back to the aromatic peroxycarboxylic acid for re-use for epoxidizing an olefin.
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