发明授权
- 专利标题: Preparation of norlabdane oxide
- 专利标题(中): 正壬醛的制备
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申请号: US905116申请日: 1997-08-01
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公开(公告)号: US5821375A公开(公告)日: 1998-10-13
- 发明人: Paul Nicholas Davey , Laurence Sidney Payne , Chi-lam Tse
- 申请人: Paul Nicholas Davey , Laurence Sidney Payne , Chi-lam Tse
- 申请人地址: NLX Naarden
- 专利权人: Quest International B.V.
- 当前专利权人: Quest International B.V.
- 当前专利权人地址: NLX Naarden
- 优先权: EPX96305708 19960802
- 主分类号: B01J27/138
- IPC分类号: B01J27/138 ; C07B61/00 ; C07D307/92 ; C11B9/00
摘要:
The invention concerns a process for preparing (-)-norlabdane oxide from sclareol oxide comprising the steps of: I converting sclareol oxide to 12-acetylnorlabdane oxide by oxidation with an organic hydroperoxide; II converting 12-acetylnorlabdane oxide to 12-acetoxy-norlabdane oxide by oxidation with an organic peracid. Step I is preferably performed with tert-butyl hydroperoxide and step II with peracetic acid. Sclareol oxide may be prepared from sclareol by ozonolysis followed by treatment with alkaline hydrogen peroxide. 12-Acetoxy-norlabdane oxide is preferably converted to norlabdane oxide by reduction with NaBH.sub.4 in the presence of a transition metal salt.
公开/授权文献
- US5308692A Fire resistant mat 公开/授权日:1994-05-03
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