发明授权
- 专利标题: Process for producing a carbonic acid diester
- 专利标题(中): 碳酸二酯的制备方法
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申请号: US896228申请日: 1997-07-17
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公开(公告)号: US5831113A公开(公告)日: 1998-11-03
- 发明人: Hiroshi Umino , Kozo Imura , Takeshi Koyama
- 申请人: Hiroshi Umino , Kozo Imura , Takeshi Koyama
- 申请人地址: JPX Tokyo
- 专利权人: JGC Corporation
- 当前专利权人: JGC Corporation
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX8-192318 19960722; JPX9-057707 19970312
- 主分类号: B01J8/18
- IPC分类号: B01J8/18 ; B01J8/24 ; C07C68/00
摘要:
A process for producing a carbonic acid diester, which comprises carrying out a reaction in a vapor phase of an alcohol, carbon monoxide and oxygen in the presence of a catalyst in a fluidized-bed reactor so that an oxidative carbonylation of the alcohol occurs, thereby obtaining a carbonic acid diester, wherein a heat of reaction is removed by the latent heat of vaporization of the alcohol as a raw material. In the process, for example, either at least part of the alcohol may be directly fed in liquid phase into the fluidized bed or cooling pipes are disposed in the fluidized bed and at least part of the alcohol is introduced in liquid phase into the cooling pipes as a heat transfer medium so that the liquid alcohol is vaporized and fed into the fluidized-bed reactor. Carbon monoxide may be introduced together with the liquid alcohol into the cooling pipes. A process of high energy efficiency realizing an effective utilization of a heat of reaction and an apparatus there for are provided in the production of a carbonic acid diester in a vapor phase with the use of a fluidized-bed reactor.
公开/授权文献
- US5191994A Water bottle crate 公开/授权日:1993-03-09
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