发明授权
US5844032A Intercalates and exfoliates formed with non-EVOH monomers, oligomers and
polymers; and EVOH composite materials containing same
失效
用非EVOH单体,低聚物和聚合物形成的插层和去角质; 和含有它的EVOH复合材料
- 专利标题: Intercalates and exfoliates formed with non-EVOH monomers, oligomers and polymers; and EVOH composite materials containing same
- 专利标题(中): 用非EVOH单体,低聚物和聚合物形成的插层和去角质; 和含有它的EVOH复合材料
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申请号: US761444申请日: 1996-12-06
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公开(公告)号: US5844032A公开(公告)日: 1998-12-01
- 发明人: Fernando Serrano , Steven J. Engman , Gary W. Beall
- 申请人: Fernando Serrano , Steven J. Engman , Gary W. Beall
- 申请人地址: IL Arlington Heights
- 专利权人: Amcol International Corporation
- 当前专利权人: Amcol International Corporation
- 当前专利权人地址: IL Arlington Heights
- 主分类号: C01B33/44
- IPC分类号: C01B33/44 ; C08K3/34 ; C08K7/00 ; C08K9/04 ; C08K9/08 ; C08L29/02 ; C08L29/04 ; C08L39/06 ; C08L71/00 ; C08L71/02 ; C11C5/00
摘要:
Nanocomposites are manufactured by combining an EVOH matrix polymer and exfoliated intercalates formed by contacting a phyllosilicate with a non-EVOH intercalant to adsorb or intercalate the intercalant between adjacent phyllosilicate platelets. Sufficient intercalant is adsorbed between adjacent phyllosilicate platelets to expand the adjacent platelets to a spacing of at least about 5 .ANG., preferably at least about 10 .ANG. (as measured after water removal), up to about 100 .ANG. and preferably in the range of about 30-40 .ANG., so that the intercalate easily can be exfoliated, e.g., when mixed with the EVOH matrix polymer melt, to provide an EVOH matrix polymer/platelet composite (nanocomposite) material that does not degrade the EVOH matrix polymer.