发明授权
- 专利标题: Method for producing purified epoxy compound
- 专利标题(中): 纯化环氧化合物的制备方法
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申请号: US892198申请日: 1997-07-14
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公开(公告)号: US5892065A公开(公告)日: 1999-04-06
- 发明人: Suketoshi Tsukamoto , Takami Ono , Hisao Ikeda , Motohiko Hidaka
- 申请人: Suketoshi Tsukamoto , Takami Ono , Hisao Ikeda , Motohiko Hidaka
- 申请人地址: JPX Tokyo
- 专利权人: Nissan Chemical Industries, Ltd.
- 当前专利权人: Nissan Chemical Industries, Ltd.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX8-190574 19960719; JPX8-263320 19961003; JPX8-263321 19961003; JPX8-293769 19961106; JPX8-293770 19961106; JPX8-314682 19961126; JPX8-314683 19961126
- 主分类号: C07D301/27
- IPC分类号: C07D301/27 ; C07D301/32 ; C07D303/16 ; C07D301/02 ; C07D405/12
摘要:
A 2,3-epoxypropyl derivative or a 2-methyl-2,3-epoxypropyl derivative of a compound having carboxyl groups or amido groups is produced as a purified product having an epoxide equivalent of 1.0 to 1.1 times the theoretical epoxide equivalent of the derivative, an ionic halogen content of 10 ppm or less, transparency when molten and a stability against increase in the epoxide equivalent when stored at 150.degree. C. for 24 hours, by a process comprising steps (A) reacting 1.2 to 60 mol of an epihalohydrin or a 2-methyl-epihalohydrin with 1 mol of active hydrogen atoms of the carboxyl or amido group of the compound in the presence of a particular catalyst, thereby forming a reaction product containing a 2-hydroxy-3-halopropyl derivative or a 2-hydroxy-2-methyl-3-halopropyl derivative, (B) dehydrohalogenating the derivative by adding to the reaction product a sufficient amount of an alkali metal hydroxide thereby forming a final slurry containing the 2,3-epoxypropyl derivative of the 2-methyl-2,3-epoxypropyl derivative and the alkali metal halide, (C) washing the final slurry or a liquid product formed by removing the alkali metal halide from the final slurry thereby forming a refined liquid containing the derivative, and (D) removing by evaporation the epihalohydrin or the 2-methyl-epihalohidrin from the refined liquid, thereby forming the 2,3-epoxypropyl derivative or the 2-methyl-2,3-epoxypropyl derivative as the purified product.
公开/授权文献
- US5260506A Drumstick having rigid ring around tip 公开/授权日:1993-11-09