The present invention relates to antistatic and adherent compositions based on polyamide, which can be employed especially for the manufacture of composite materials and articles, such as multilayer pipes and/or conduits for conveying and/or storing hydrocarbons. The compositions contain carbon black and are employed for the production of pipes, containers and drums including:an inner layer in contact with the hydrocarbons, based on the said antistatic and adherent composition,a middle layer made of fluoropolymer, preferably of polyvinylidene fluoride, andan outer layer of polyamide,these layers being bonded to each other respectively by layers of adhesive binder. The invention also relates to a process for preparing these items.