发明授权
- 专利标题： Selective hydrogenation catalysts containing palladium, also tin and/or lead, and the preparation and use thereof
- 专利标题（中）： 含钯，还有锡和/或铅的选择性氢化催化剂及其制备和应用
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申请号： US964129申请日： 1997-11-06
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公开(公告)号： US5955397A公开(公告)日： 1999-09-21
- 发明人: Blaise Didillon , Charles Cameron , Christophe Gautreau
- 申请人： Blaise Didillon , Charles Cameron , Christophe Gautreau
- 申请人地址： FRX Rueil Malmaison Cedex
- 专利权人： Institut Francais du Petrole
- 当前专利权人： Institut Francais du Petrole
- 当前专利权人地址： FRX Rueil Malmaison Cedex
- 优先权： FRX9613576 19961107
- 主分类号： B01J23/44
- IPC分类号： B01J23/44 ; B01J23/62 ; B01J37/02 ; C07B61/00 ; C07C5/05 ; C07C11/08 ; C07C29/17 ; C10G45/40
摘要：
A particulate selective hydrogenation catalyst for transforming unsaturated diolefinic hydrocarbons to .alpha.-olefinic hydrocarbons is described, for the hydrogenation of diolefinic compounds to .alpha.-olefinic compounds at rates which are at least 1.5 times higher than the rate of hydrogenation of .alpha.-olefinic hydrocarbons to saturated compounds. The catalyst contains palladium distributed at the periphery of particles (spherules or extrudates), and at least one element selected from tin and lead. Further, the tin and/or lead is advantageously distributed at the periphery of the spherules or extrudates. The catalyst preparation is also described, as well as a process for selective hydrogenation of diolefins to .alpha.-olefins using the catalyst.