发明授权
US5958359A Process for treating H.sub.2 S-lean streams, with recycle of SOx from
burner
失效
用于处理富含H2S的物流,从燃烧器回收SOx的方法
- 专利标题: Process for treating H.sub.2 S-lean streams, with recycle of SOx from burner
- 专利标题(中): 用于处理富含H2S的物流,从燃烧器回收SOx的方法
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申请号: US992168申请日: 1997-12-17
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公开(公告)号: US5958359A公开(公告)日: 1999-09-28
- 发明人: John S. Buchanan , Khushrav E. Nariman
- 申请人: John S. Buchanan , Khushrav E. Nariman
- 申请人地址: VA Fairfax
- 专利权人: Mobil Oil Corporation
- 当前专利权人: Mobil Oil Corporation
- 当前专利权人地址: VA Fairfax
- 主分类号: B01D53/52
- IPC分类号: B01D53/52 ; B01D53/75 ; B01D53/81 ; B01J20/06 ; C01B17/04
摘要:
This invention is directed to an improved process for conversion of H.sub.2 S to sulfur, using MOST(Mobil Offgas Sulfur Treatment) catalyst or sorbent. The sorbent is typically a magnesium-aluminate spinel, with oxidation promoters such as ceria and vanadia. H.sub.2 S from the feed gas is used to regenerate sulfated sorbent, simultaneously producing elemental sulfur which is then condensed out. The improvement involves recycling a portion of the effluent from a downstream burner to mix with the feed to the sorbent. Thus some of the stoichiometric oxygen required for conversion of H.sub.2 S to S is supplied in the form of SO.sub.2 by this pre-combustion step, instead of coming totally from the oxidized/sulfated solid sorbent. This can decrease the amount of sorbent required, as well as the frequency of regenerations, thus reducing process cost. The hot recycle gas also helps to heat the feed stream.
公开/授权文献
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