Invention Grant
US5958588A Process for preparing alkali metal cyanide and alkaline earth metal cyanide granules and the high purity alkali metal cyanide granules obtainable thereby 失效
制备碱金属氰化物和碱土金属氰化物颗粒的方法以及由此获得的高纯碱金属氰化物颗粒

Process for preparing alkali metal cyanide and alkaline earth metal
cyanide granules and the high purity alkali metal cyanide granules
obtainable thereby
Abstract:
A process for the direct preparation of alkali metal cyanide and alkaline earth metal cyanide granules from an HCN-containing gas and an aqueous solution or suspension of an alkali metal or alkaline earth metal hydroxide. The reaction is performed in a reactor for fluidized bed spray granulation, wherein a solution or suspension of the hydroxide is sprayed onto seed granules of the cyanide being prepared and at the same time a hydrogen cyanide-containing gas is supplied to the reactor and water is evaporated by means of a fluidizing gas. The preferred fluidizing gas is steam. The reaction gases from a BMA or Andrussow process may be quenched with water and the gas mixture used as fluidizing gas. By using a CO.sub.2 -free HCN-containing gas, alkali metal cyanide granules with advantageous properties, including a combined concentration of alkali metal carbonate and alkali metal formate of less then 0.4 wt. %, are obtainable.
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